TY - JOUR
T1 - Early metal di- and tricyanometalates
T2 - Useful building blocks for constructing magnetic clusters
AU - Li, Dongfeng
AU - Parkin, Sean
AU - Wang, Guangbin
AU - Yee, Gordon T.
AU - Holmes, Stephen M.
N1 - Copyright:
Copyright 2011 Elsevier B.V., All rights reserved.
PY - 2006/4/3
Y1 - 2006/4/3
N2 - Treatment of mer-VCI3(THF)3 with KTp* [Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate], followed by [NEt4]CN in acetonitrile, affords [NEt4][(Tp*)VIII(CN)3]·H 2O (1·H2O); aerobic oxidation affords [NEt4][(Tp*)VIV(O)(CN)2] (2). Subsequent treatment of 2 with MnII-(OTf)2 (OTf = trifluoromethanesulfonate) and 2,2′-bipyridine affords {[(Tp*)V(O)(CN)2]2[MnII(bipy) 2]2[OTf]2}·2MeCN (3). Magnetic measurements indicate that 1-3 exhibit S = 1, 1/2, and 4 spin ground states, respectively.
AB - Treatment of mer-VCI3(THF)3 with KTp* [Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate], followed by [NEt4]CN in acetonitrile, affords [NEt4][(Tp*)VIII(CN)3]·H 2O (1·H2O); aerobic oxidation affords [NEt4][(Tp*)VIV(O)(CN)2] (2). Subsequent treatment of 2 with MnII-(OTf)2 (OTf = trifluoromethanesulfonate) and 2,2′-bipyridine affords {[(Tp*)V(O)(CN)2]2[MnII(bipy) 2]2[OTf]2}·2MeCN (3). Magnetic measurements indicate that 1-3 exhibit S = 1, 1/2, and 4 spin ground states, respectively.
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U2 - 10.1021/ic051630a
DO - 10.1021/ic051630a
M3 - Article
C2 - 16562931
AN - SCOPUS:33645951418
VL - 45
SP - 2773
EP - 2775
IS - 7
ER -