Electrochemistry and transport phenomena of the lithium-silicon system: Modeling and open questions

Mark Verbrugge; Daniel Baker; Xingcheng Xiao; Qinglin Zhang; Yang Tse Cheng

Electrochemistry and transport phenomena of the lithium-silicon system: Modeling and open questions

Mark Verbrugge, Daniel Baker, Xingcheng Xiao, Qinglin Zhang, Yang Tse Cheng

Research output: Contribution to conference › Paper › peer-review

Abstract

Derived an equation system for the treatment of electrode materials that undergo large volume changes during operation. Applied to a thin-film Li-Si system, wherein a volume change of about 270% is observed relative to pure Si and Li3.75Si. Employed linear-sweep voltammetry with end-potential holds so as to separate lithiation and delithiation processes. Reasonable model-experiment agreement. Key open questions identified.

Original language	English
State	Published - 2015
Event	32nd Annual International Battery Seminar and Exhibit - Fort Lauderdale, United States Duration: Mar 9 2015 → Mar 12 2015

Conference

Conference	32nd Annual International Battery Seminar and Exhibit
Country/Territory	United States
City	Fort Lauderdale
Period	3/9/15 → 3/12/15

ASJC Scopus subject areas

Fuel Technology
Energy Engineering and Power Technology

Cite this

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title = "Electrochemistry and transport phenomena of the lithium-silicon system: Modeling and open questions",

abstract = "Derived an equation system for the treatment of electrode materials that undergo large volume changes during operation. Applied to a thin-film Li-Si system, wherein a volume change of about 270% is observed relative to pure Si and Li3.75Si. Employed linear-sweep voltammetry with end-potential holds so as to separate lithiation and delithiation processes. Reasonable model-experiment agreement. Key open questions identified.",

author = "Mark Verbrugge and Daniel Baker and Xingcheng Xiao and Qinglin Zhang and Cheng, {Yang Tse}",

year = "2015",

language = "English",

note = "32nd Annual International Battery Seminar and Exhibit ; Conference date: 09-03-2015 Through 12-03-2015",

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TY - CONF

T1 - Electrochemistry and transport phenomena of the lithium-silicon system

T2 - 32nd Annual International Battery Seminar and Exhibit

AU - Verbrugge, Mark

AU - Baker, Daniel

AU - Xiao, Xingcheng

AU - Zhang, Qinglin

AU - Cheng, Yang Tse

PY - 2015

Y1 - 2015

N2 - Derived an equation system for the treatment of electrode materials that undergo large volume changes during operation. Applied to a thin-film Li-Si system, wherein a volume change of about 270% is observed relative to pure Si and Li3.75Si. Employed linear-sweep voltammetry with end-potential holds so as to separate lithiation and delithiation processes. Reasonable model-experiment agreement. Key open questions identified.

AB - Derived an equation system for the treatment of electrode materials that undergo large volume changes during operation. Applied to a thin-film Li-Si system, wherein a volume change of about 270% is observed relative to pure Si and Li3.75Si. Employed linear-sweep voltammetry with end-potential holds so as to separate lithiation and delithiation processes. Reasonable model-experiment agreement. Key open questions identified.

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UR - http://www.scopus.com/inward/citedby.url?scp=84962810196&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:84962810196

Y2 - 9 March 2015 through 12 March 2015

ER -

Electrochemistry and transport phenomena of the lithium-silicon system: Modeling and open questions

Abstract

Conference

ASJC Scopus subject areas

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