Ethylene/vinyl acetate copolymers via acyclic diene metathesis polymerization. examining the effect of "long" precise ethylene run lengths

Mark D. Watson; Kenneth B. Wagener

doi:10.1021/ma9920689

Ethylene/vinyl acetate copolymers via acyclic diene metathesis polymerization. examining the effect of "long" precise ethylene run lengths

Mark D. Watson, Kenneth B. Wagener

Chemistry

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

Tandem acyclic diene metathesis (ADMET) polymerization/catalytic hydrogénation has been exploited to synthesize copolymers modeling ethylene/vinyl acetate (EVA) materials. A series of four sequence-ordered ethylene-co-vinyl acetate copolymers were prepared possessing precisely defined ethylene run lengths from 18 to 26 carbons. Use of the well-defined ADMET reaction in combination with a quantitative olefin-hydrogen technique generates well-defined EVA's, all of which are semicrystalline with a linear relationship between ethylene run length and melting temperature. All polymers except -that with the lowest ethylene run length are film and fiber forming.

Original language	English
Pages (from-to)	5411-5417
Number of pages	7
Journal	Macromolecules
Volume	33
Issue number	15
DOIs	https://doi.org/10.1021/ma9920689
State	Published - Jul 25 2000

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma9920689

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N2 - Tandem acyclic diene metathesis (ADMET) polymerization/catalytic hydrogénation has been exploited to synthesize copolymers modeling ethylene/vinyl acetate (EVA) materials. A series of four sequence-ordered ethylene-co-vinyl acetate copolymers were prepared possessing precisely defined ethylene run lengths from 18 to 26 carbons. Use of the well-defined ADMET reaction in combination with a quantitative olefin-hydrogen technique generates well-defined EVA's, all of which are semicrystalline with a linear relationship between ethylene run length and melting temperature. All polymers except -that with the lowest ethylene run length are film and fiber forming.

AB - Tandem acyclic diene metathesis (ADMET) polymerization/catalytic hydrogénation has been exploited to synthesize copolymers modeling ethylene/vinyl acetate (EVA) materials. A series of four sequence-ordered ethylene-co-vinyl acetate copolymers were prepared possessing precisely defined ethylene run lengths from 18 to 26 carbons. Use of the well-defined ADMET reaction in combination with a quantitative olefin-hydrogen technique generates well-defined EVA's, all of which are semicrystalline with a linear relationship between ethylene run length and melting temperature. All polymers except -that with the lowest ethylene run length are film and fiber forming.

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Ethylene/vinyl acetate copolymers via acyclic diene metathesis polymerization. examining the effect of "long" precise ethylene run lengths

Abstract

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