Exploratory photochemistry of iodinated aromatic azides

David S. Watt; Kenji Kawada; Elisa Leyva; Matthew S. Platz

doi:10.1016/S0040-4039(00)95273-0

Exploratory photochemistry of iodinated aromatic azides

David S. Watt, Kenji Kawada, Elisa Leyva, Matthew S. Platz

Molecular and Cellular Biochemistry

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

In contrast to the photolysis of p-toluyl azide, photolysis of ortho- or meta-iodo substituted p-toluyl azide in the presence of nucleophilic trapping agents produced the corresponding triplet nitrene which led to the simple aniline products and not to the dehydroazepine-nucleophile adducts.

Original language	English
Pages (from-to)	899-902
Number of pages	4
Journal	Tetrahedron Letters
Volume	30
Issue number	8
DOIs	https://doi.org/10.1016/S0040-4039(00)95273-0
State	Published - 1989

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)95273-0

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title = "Exploratory photochemistry of iodinated aromatic azides",

abstract = "In contrast to the photolysis of p-toluyl azide, photolysis of ortho- or meta-iodo substituted p-toluyl azide in the presence of nucleophilic trapping agents produced the corresponding triplet nitrene which led to the simple aniline products and not to the dehydroazepine-nucleophile adducts.",

author = "Watt, {David S.} and Kenji Kawada and Elisa Leyva and Platz, {Matthew S.}",

year = "1989",

doi = "10.1016/S0040-4039(00)95273-0",

language = "English",

volume = "30",

pages = "899--902",

number = "8",

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TY - JOUR

T1 - Exploratory photochemistry of iodinated aromatic azides

AU - Watt, David S.

AU - Kawada, Kenji

AU - Leyva, Elisa

AU - Platz, Matthew S.

PY - 1989

Y1 - 1989

N2 - In contrast to the photolysis of p-toluyl azide, photolysis of ortho- or meta-iodo substituted p-toluyl azide in the presence of nucleophilic trapping agents produced the corresponding triplet nitrene which led to the simple aniline products and not to the dehydroazepine-nucleophile adducts.

AB - In contrast to the photolysis of p-toluyl azide, photolysis of ortho- or meta-iodo substituted p-toluyl azide in the presence of nucleophilic trapping agents produced the corresponding triplet nitrene which led to the simple aniline products and not to the dehydroazepine-nucleophile adducts.

UR - http://www.scopus.com/inward/record.url?scp=0001151962&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001151962&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)95273-0

DO - 10.1016/S0040-4039(00)95273-0

M3 - Article

AN - SCOPUS:0001151962

SN - 0040-4039

VL - 30

SP - 899

EP - 902

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 8

ER -

Exploratory photochemistry of iodinated aromatic azides

Abstract

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