Factors affecting cation formation in group 13 alkyl halide complexes

David Atwood; Jolin Jegier

doi:10.1039/cc9960001507

Factors affecting cation formation in group 13 alkyl halide complexes

David Atwood, Jolin Jegier

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21 Scopus citations

Abstract

The demarcation for the formation of cationic aluminium complexes is the transition between the use of chloride as a ligand (Me₂AlCl-NH₂Bu^t 1) and the relatively more polarizable bromide {[Me₂Al(NH₂Bu^t)₂]Br 2} as determined by X-ray diffractometry.

Original language	English
Pages (from-to)	1507-1508
Number of pages	2
Journal	Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/cc9960001507
State	Published - 1996

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Factors affecting cation formation in group 13 alkyl halide complexes",

abstract = "The demarcation for the formation of cationic aluminium complexes is the transition between the use of chloride as a ligand (Me2AlCl-NH2But 1) and the relatively more polarizable bromide {[Me2Al(NH2But)2]Br 2} as determined by X-ray diffractometry.",

author = "David Atwood and Jolin Jegier",

year = "1996",

doi = "10.1039/cc9960001507",

language = "English",

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number = "13",

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T1 - Factors affecting cation formation in group 13 alkyl halide complexes

AU - Atwood, David

AU - Jegier, Jolin

PY - 1996

Y1 - 1996

N2 - The demarcation for the formation of cationic aluminium complexes is the transition between the use of chloride as a ligand (Me2AlCl-NH2But 1) and the relatively more polarizable bromide {[Me2Al(NH2But)2]Br 2} as determined by X-ray diffractometry.

AB - The demarcation for the formation of cationic aluminium complexes is the transition between the use of chloride as a ligand (Me2AlCl-NH2But 1) and the relatively more polarizable bromide {[Me2Al(NH2But)2]Br 2} as determined by X-ray diffractometry.

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U2 - 10.1039/cc9960001507

DO - 10.1039/cc9960001507

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EP - 1508

JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -

Factors affecting cation formation in group 13 alkyl halide complexes

Abstract

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