Abstract
A generalized relationship to describe bond coupling constants is introduced. This expression includes the contributions for hybrid orbitals and the net atomic charges. The resulting expression provides an excellent description of directly bonded CH coupling constants. This equation is suitable both for hydrocarbons and for molecules with I+ and I− substituents.
Original language | English |
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Pages (from-to) | 465-467 |
Number of pages | 3 |
Journal | Magnetic Resonance in Chemistry |
Volume | 32 |
Issue number | 8 |
DOIs | |
State | Published - Aug 1994 |
Keywords
- Hybrid orbital
- Maximum bond order hybrid orbital
- NMR
- Net atomic charge
- Nuclear spin‐spin coupling constant
ASJC Scopus subject areas
- Chemistry (all)
- Materials Science (all)