Halogen-containing tetrametallic aluminium alkoxides

Amitabha Mitra, Yuzhong Wang, Sean Parkin, David Atwood

Research output: Contribution to journalArticlepeer-review

3 Citations (SciVal)

Abstract

New halogen-containing tetrametallic aluminium alkoxides of formula [Al((µ-OEt)2AlMeCl)3] (2-cis; 2-trans), and [Al((µ-OEt)2AlBr2)3] (4), have been synthesized by combining Al(OEt)3 and Me2AlCl (for 2) or EtAlBr2 (for 4). They were fully characterized by(1H,27Al) NMR, IR, mp, elemental analysis, and single-crystal X-ray diffractometry. The chloride analogue of 4, [Al((µ-OEt)2AlCl2)3] (3), prepared previously using a different route, was also prepared here by combining Al(OEt)3 and EtAlCl2.

Original languageEnglish
Pages (from-to)1037-1042
Number of pages6
JournalJournal of the Chemical Society, Dalton Transactions
Issue number8
DOIs
StatePublished - Jan 7 2008

ASJC Scopus subject areas

  • Chemistry (all)

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