Halogen-containing tetrametallic aluminium alkoxides

Amitabha Mitra; Yuzhong Wang; Sean Parkin; David Atwood

doi:10.1039/b716812h

Halogen-containing tetrametallic aluminium alkoxides

Amitabha Mitra, Yuzhong Wang, Sean Parkin, David Atwood

Chemistry

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3 Citations (SciVal)

Abstract

New halogen-containing tetrametallic aluminium alkoxides of formula [Al{(μ-OEt)₂AlMeCl}₃] (2-cis; 2-trans), and [Al{(μ-OEt)₂AlBr₂}₃] (4), have been synthesized by combining Al(OEt)₃ and Me₂AlCl (for 2) or EtAlBr₂ (for 4). They were fully characterized by (¹H, ²⁷Al) NMR, IR, mp, elemental analysis, and single-crystal X-ray diffractometry. The chloride analogue of 4, [Al{(μ-OEt)₂AlCl ₂}₃] (3), prepared previously using a different route, was also prepared here by combining Al(OEt)₃ and EtAlCl₂.

Original language	English
Pages (from-to)	1037-1042
Number of pages	6
Journal	Dalton Transactions
Issue number	8
DOIs	https://doi.org/10.1039/b716812h
State	Published - 2008

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/b716812h

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@article{ccb10035c22340b5a18ff9465242b9fb,

title = "Halogen-containing tetrametallic aluminium alkoxides",

abstract = "New halogen-containing tetrametallic aluminium alkoxides of formula [Al\{(μ-OEt)2AlMeCl\}3] (2-cis; 2-trans), and [Al\{(μ-OEt)2AlBr2\}3] (4), have been synthesized by combining Al(OEt)3 and Me2AlCl (for 2) or EtAlBr2 (for 4). They were fully characterized by (1H, 27Al) NMR, IR, mp, elemental analysis, and single-crystal X-ray diffractometry. The chloride analogue of 4, [Al\{(μ-OEt)2AlCl 2\}3] (3), prepared previously using a different route, was also prepared here by combining Al(OEt)3 and EtAlCl2.",

author = "Amitabha Mitra and Yuzhong Wang and Sean Parkin and David Atwood",

year = "2008",

doi = "10.1039/b716812h",

language = "English",

pages = "1037--1042",

number = "8",

}

TY - JOUR

T1 - Halogen-containing tetrametallic aluminium alkoxides

AU - Mitra, Amitabha

AU - Wang, Yuzhong

AU - Parkin, Sean

AU - Atwood, David

PY - 2008

Y1 - 2008

N2 - New halogen-containing tetrametallic aluminium alkoxides of formula [Al{(μ-OEt)2AlMeCl}3] (2-cis; 2-trans), and [Al{(μ-OEt)2AlBr2}3] (4), have been synthesized by combining Al(OEt)3 and Me2AlCl (for 2) or EtAlBr2 (for 4). They were fully characterized by (1H, 27Al) NMR, IR, mp, elemental analysis, and single-crystal X-ray diffractometry. The chloride analogue of 4, [Al{(μ-OEt)2AlCl 2}3] (3), prepared previously using a different route, was also prepared here by combining Al(OEt)3 and EtAlCl2.

AB - New halogen-containing tetrametallic aluminium alkoxides of formula [Al{(μ-OEt)2AlMeCl}3] (2-cis; 2-trans), and [Al{(μ-OEt)2AlBr2}3] (4), have been synthesized by combining Al(OEt)3 and Me2AlCl (for 2) or EtAlBr2 (for 4). They were fully characterized by (1H, 27Al) NMR, IR, mp, elemental analysis, and single-crystal X-ray diffractometry. The chloride analogue of 4, [Al{(μ-OEt)2AlCl 2}3] (3), prepared previously using a different route, was also prepared here by combining Al(OEt)3 and EtAlCl2.

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U2 - 10.1039/b716812h

DO - 10.1039/b716812h

M3 - Article

C2 - 18274684

AN - SCOPUS:39349104368

SN - 1477-9226

SP - 1037

EP - 1042

JO - Dalton Transactions

JF - Dalton Transactions

IS - 8

ER -

Halogen-containing tetrametallic aluminium alkoxides

Abstract

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