High-performance activated carbons for supercapacitor: Effects of porous structures, heteroatom doping, and morphology

Xinyu Cai, Qingyuan Ren, Wei Sun, Fuqian Yang

Research output: Contribution to journalArticlepeer-review

25 Scopus citations

Abstract

In this work, we prepare a series of activated carbons (ACs) of different morphologies, porous structures, and oxygen contents from glucose with hydrothermal synthesis (HTS) followed by a one-step (H2O-steam or KOH) or two-step (H2O-steam-KOH or KOH-H2O-steam) activation. The largest surface area of the prepared ACs is more than 3400 m2/g, and the corresponding mesopore volume is 1.21 cm3/g. The fraction of oxygen in the ACs varies in a range of 3.94 to 9.9 at%. The electrochemical performance of the symmetric supercapacitor cells (SCs) made from the as-prepared ACs is characterized in different aqueous electrolytes. The optimum capacitance of the SCs is 421 F/g at 0.5 A/g and 304 F/g at 10 A/g. The oxygen-enriched functional groups have limited contribution to the energy storage for the SCs with neutral electrolyte and profound effects on the increase of the energy storage for the SCs with strong acidic and alkaline electrolytes. The processing routes developed in this work likely open an avenue to tailor the structures and oxygen-enriched functional groups of ACs.

Original languageEnglish
Pages (from-to)21414-21434
Number of pages21
JournalInternational Journal of Energy Research
Volume45
Issue number15
DOIs
StatePublished - Dec 2021

Bibliographical note

Publisher Copyright:
© 2021 John Wiley & Sons Ltd.

Keywords

  • activated carbons
  • electrochemical performance
  • oxygen-enriched functional groups
  • porous structure
  • supercapacitor
  • two-step activation

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Nuclear Energy and Engineering
  • Fuel Technology
  • Energy Engineering and Power Technology

Fingerprint

Dive into the research topics of 'High-performance activated carbons for supercapacitor: Effects of porous structures, heteroatom doping, and morphology'. Together they form a unique fingerprint.

Cite this