TY - JOUR
T1 - Hydrogen bonding in macrocyclic receptor systems
AU - Lynn, Bert C.
AU - Tsfsarskaja, Mara
AU - Schall, Otto
AU - Hernandez, Jeanette C.
AU - Watanabe, Shigeru
AU - Kaifer, Angel
AU - Takailashi, Toshio
AU - Gokel, George W.
N1 - Funding Information:
We thank the NIH for a grant (GM 36262) that supported this work.
PY - 1993
Y1 - 1993
N2 - The interactions of macrocyclic polyethers with alkali and alkaline earth cations have been well studied and much about their chemistry is now well understood. Less well examined or comprehended are hydrogen bond interactions. A combination of ion selective electrode binding constant determination techniques and fast atom bombardment mass spectrometry are brought to bear on this problem. It is found that all-oxygen crown ethers and their derivatives exhibit quite different complexation behaviour with ammonium salts than do their various azacrown counterparts.
AB - The interactions of macrocyclic polyethers with alkali and alkaline earth cations have been well studied and much about their chemistry is now well understood. Less well examined or comprehended are hydrogen bond interactions. A combination of ion selective electrode binding constant determination techniques and fast atom bombardment mass spectrometry are brought to bear on this problem. It is found that all-oxygen crown ethers and their derivatives exhibit quite different complexation behaviour with ammonium salts than do their various azacrown counterparts.
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U2 - 10.1080/10610279308035168
DO - 10.1080/10610279308035168
M3 - Article
AN - SCOPUS:0001701692
SN - 1061-0278
VL - 1
SP - 253
EP - 260
JO - Supramolecular Chemistry
JF - Supramolecular Chemistry
IS - 3-4
ER -