Hydrothermal Synthesis and Characterization of Hexavanadium Polyoxo Alkoxide Anion Clusters: Crystal Structures of the Vanadium(IV) Species Ba[V6O7(OH)3{(OCH2)3CCH3}3]·3H2O and Na2[V6O7{(OCH2)3CCH2CH3}4], of the Mixed-Valence Complex (Me3NH)[VIV5VVO7(OH)3{(OCH2)3CCH3}3], and of the Fluoro Derivative Na[V6O6F(OH)3{(OCH2)3CCH3}3]·3H2O

M. Ishaque Khan, Qin Chen, Hakon Höpe, Sean Parkin, Charles J. O'Connor, Jon Zubieta

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Chemistry