Influence of phenoxy-terminated short-chain pendant groups on gas transport properties of cross-linked poly(ethylene oxide) copolymers

Victor A. Kusuma; Scott Matteucci; Benny D. Freeman; Michael K. Danquah; Douglass S. Kalika

doi:10.1016/j.memsci.2009.05.043

Influence of phenoxy-terminated short-chain pendant groups on gas transport properties of cross-linked poly(ethylene oxide) copolymers

Victor A. Kusuma, Scott Matteucci, Benny D. Freeman, Michael K. Danquah, Douglass S. Kalika

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

Gas transport properties of rubbery cross-linked poly(ethylene oxide) films containing short phenoxy-terminated pendant chains are reported. Poly(ethylene glycol) diacrylate (PEGDA) was UV-polymerized with poly(ethylene glycol) phenyl ether acrylate co-monomers of two different ethylene oxide repeat unit lengths: n = 2 (DEGPEA) and n = 4 (PEGPEA). Although fractional free volume increased with increasing co-monomer concentration, gas permeability did not rise accordingly. For instance, while FFV increased from 0.120 to 0.135 in both series of copolymers, CO₂ permeability went from 110 to 35 barrer (DEGPEA) or to 100 barrer (PEGPEA). At the same time, glass transition temperature increased from -37 to -12 °C (DEGPEA) or to -28 °C (PEGPEA). The observed decrease in chain mobility with phenoxy-terminated co-monomer content indicated by increasing glass-rubber transition temperature apparently had a stronger influence on gas transport properties than the increase in fractional free volume.

Original language	English
Pages (from-to)	84-95
Number of pages	12
Journal	Journal of Membrane Science
Volume	341
Issue number	1-2
DOIs	https://doi.org/10.1016/j.memsci.2009.05.043
State	Published - Sep 30 2009

Bibliographical note

Funding Information:
We gratefully acknowledge partial support of this work by the U.S. Department of Energy (Grant DE-FG02-02ER15362) and by the U.S. National Science Foundation (Grant CBET-0515425). Activities at the University of Kentucky were supported by a grant from the Kentucky Science and Engineering Foundation as per Grant Agreement KSEF-148-502-05-130 with the Kentucky Science and Technology Corporation. The authors would like to thank Dr. Angel E. Lozano of Instituto de Ciencia y Tecnología de Polímeros (Madrid, Spain) and Dr. Donald R. Paul of the University of Texas at Austin for helpful discussions regarding some aspects of this work.

Funding

We gratefully acknowledge partial support of this work by the U.S. Department of Energy (Grant DE-FG02-02ER15362) and by the U.S. National Science Foundation (Grant CBET-0515425). Activities at the University of Kentucky were supported by a grant from the Kentucky Science and Engineering Foundation as per Grant Agreement KSEF-148-502-05-130 with the Kentucky Science and Technology Corporation. The authors would like to thank Dr. Angel E. Lozano of Instituto de Ciencia y Tecnología de Polímeros (Madrid, Spain) and Dr. Donald R. Paul of the University of Texas at Austin for helpful discussions regarding some aspects of this work.

Funders	Funder number
Kentucky Science and Technology Corporation
U.S. National Science Foundation (NSF)	CBET-0515425
Michigan State University-U.S. Department of Energy (MSU-DOE) Plant Research Laboratory	DE-FG02-02ER15362
Kentucky Science and Engineering Foundation	KSEF-148-502-05-130

Keywords

Chain mobility
Cross-linked poly(ethylene oxide)
Fractional free volume
Light gas separation
Structure/property relationship

ASJC Scopus subject areas

Biochemistry
General Materials Science
Physical and Theoretical Chemistry
Filtration and Separation

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10.1016/j.memsci.2009.05.043

Cite this

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title = "Influence of phenoxy-terminated short-chain pendant groups on gas transport properties of cross-linked poly(ethylene oxide) copolymers",

abstract = "Gas transport properties of rubbery cross-linked poly(ethylene oxide) films containing short phenoxy-terminated pendant chains are reported. Poly(ethylene glycol) diacrylate (PEGDA) was UV-polymerized with poly(ethylene glycol) phenyl ether acrylate co-monomers of two different ethylene oxide repeat unit lengths: n = 2 (DEGPEA) and n = 4 (PEGPEA). Although fractional free volume increased with increasing co-monomer concentration, gas permeability did not rise accordingly. For instance, while FFV increased from 0.120 to 0.135 in both series of copolymers, CO2 permeability went from 110 to 35 barrer (DEGPEA) or to 100 barrer (PEGPEA). At the same time, glass transition temperature increased from -37 to -12 °C (DEGPEA) or to -28 °C (PEGPEA). The observed decrease in chain mobility with phenoxy-terminated co-monomer content indicated by increasing glass-rubber transition temperature apparently had a stronger influence on gas transport properties than the increase in fractional free volume.",

keywords = "Chain mobility, Cross-linked poly(ethylene oxide), Fractional free volume, Light gas separation, Structure/property relationship",

author = "Kusuma, {Victor A.} and Scott Matteucci and Freeman, {Benny D.} and Danquah, {Michael K.} and Kalika, {Douglass S.}",

note = "Funding Information: We gratefully acknowledge partial support of this work by the U.S. Department of Energy (Grant DE-FG02-02ER15362) and by the U.S. National Science Foundation (Grant CBET-0515425). Activities at the University of Kentucky were supported by a grant from the Kentucky Science and Engineering Foundation as per Grant Agreement KSEF-148-502-05-130 with the Kentucky Science and Technology Corporation. The authors would like to thank Dr. Angel E. Lozano of Instituto de Ciencia y Tecnolog{\'i}a de Pol{\'i}meros (Madrid, Spain) and Dr. Donald R. Paul of the University of Texas at Austin for helpful discussions regarding some aspects of this work. ",

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AU - Kusuma, Victor A.

AU - Matteucci, Scott

AU - Freeman, Benny D.

AU - Danquah, Michael K.

AU - Kalika, Douglass S.

N1 - Funding Information: We gratefully acknowledge partial support of this work by the U.S. Department of Energy (Grant DE-FG02-02ER15362) and by the U.S. National Science Foundation (Grant CBET-0515425). Activities at the University of Kentucky were supported by a grant from the Kentucky Science and Engineering Foundation as per Grant Agreement KSEF-148-502-05-130 with the Kentucky Science and Technology Corporation. The authors would like to thank Dr. Angel E. Lozano of Instituto de Ciencia y Tecnología de Polímeros (Madrid, Spain) and Dr. Donald R. Paul of the University of Texas at Austin for helpful discussions regarding some aspects of this work.

PY - 2009/9/30

Y1 - 2009/9/30

N2 - Gas transport properties of rubbery cross-linked poly(ethylene oxide) films containing short phenoxy-terminated pendant chains are reported. Poly(ethylene glycol) diacrylate (PEGDA) was UV-polymerized with poly(ethylene glycol) phenyl ether acrylate co-monomers of two different ethylene oxide repeat unit lengths: n = 2 (DEGPEA) and n = 4 (PEGPEA). Although fractional free volume increased with increasing co-monomer concentration, gas permeability did not rise accordingly. For instance, while FFV increased from 0.120 to 0.135 in both series of copolymers, CO2 permeability went from 110 to 35 barrer (DEGPEA) or to 100 barrer (PEGPEA). At the same time, glass transition temperature increased from -37 to -12 °C (DEGPEA) or to -28 °C (PEGPEA). The observed decrease in chain mobility with phenoxy-terminated co-monomer content indicated by increasing glass-rubber transition temperature apparently had a stronger influence on gas transport properties than the increase in fractional free volume.

AB - Gas transport properties of rubbery cross-linked poly(ethylene oxide) films containing short phenoxy-terminated pendant chains are reported. Poly(ethylene glycol) diacrylate (PEGDA) was UV-polymerized with poly(ethylene glycol) phenyl ether acrylate co-monomers of two different ethylene oxide repeat unit lengths: n = 2 (DEGPEA) and n = 4 (PEGPEA). Although fractional free volume increased with increasing co-monomer concentration, gas permeability did not rise accordingly. For instance, while FFV increased from 0.120 to 0.135 in both series of copolymers, CO2 permeability went from 110 to 35 barrer (DEGPEA) or to 100 barrer (PEGPEA). At the same time, glass transition temperature increased from -37 to -12 °C (DEGPEA) or to -28 °C (PEGPEA). The observed decrease in chain mobility with phenoxy-terminated co-monomer content indicated by increasing glass-rubber transition temperature apparently had a stronger influence on gas transport properties than the increase in fractional free volume.

KW - Chain mobility

KW - Cross-linked poly(ethylene oxide)

KW - Fractional free volume

KW - Light gas separation

KW - Structure/property relationship

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Influence of phenoxy-terminated short-chain pendant groups on gas transport properties of cross-linked poly(ethylene oxide) copolymers

Abstract

Bibliographical note

Funding

Keywords

ASJC Scopus subject areas

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