Abstract
Ilmenite ore has been widely accepted to be a cost-effective oxygen carrier (OC) of Chemical Looping Combustion (CLC) for CO2 capture. The focus of this study is to investigate into the influences of chemical impact, thermal variation and ageing effect on microstructure and performance evolutions of ilmenite OCs. Iron element migration, crystallinity and morphology alterations, and irreversible change of chemical composition were identified to be the major aspects responsible for gradual microstructural evolutions of Ilmenite OCs. Iron element migration from bulk materials to particle surface, occurring during the oxidation step of redox cycles, was of temperature- and O2 concentration- dependences. A schematic diagram was developed to explain the pathways of irreversible iron migration and alteration of chemical composition in redox cycle reactions. By lowering phase interaction between Fe2TiO5 and TiO2, the cycled thermal shock (due to reaction and processing in CLC) promotes the iron element concentration on OC particle surface and the ilmenite OC reactivity.
Original language | English |
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Article number | 107139 |
Journal | Fuel Processing Technology |
Volume | 228 |
DOIs | |
State | Published - Apr 2022 |
Bibliographical note
Publisher Copyright:© 2021
Keywords
- Chemical-Looping Combustion
- Ilmenite oxygen carriers
- Microstructural evolution
- Redox cycle
- Thermal conditions
ASJC Scopus subject areas
- General Chemical Engineering
- Fuel Technology
- Energy Engineering and Power Technology