Lignin derived hydrophobic deep eutectic solvents as sustainable extractants

Yuxuan Zhang, Qi Qiao, Usman L. Abbas, Jun Liu, Yi Zheng, Christopher Jones, Qing Shao, Jian Shi

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

Solvent innovation has become a central task for improving the sustainability of chemical processes1. Deep eutectic solvents (DESs) emerge as environmentally friendly alternatives to toxic and volatile organic solvents. One appealing aspect for DESs is that they can be synthesized using naturally occurring compounds from biomass. Herein, we prepared novel hydrophobic DESs based on lignin derivatives and characterized their physicochemical properties including density, viscosity, and thermal behavior. The results showed that five lignin-derived hydrophobic DESs made from menthol, thymol, and 2,6-dimethoxyphenol were promising as green solvents due to their low viscosities and environmentally friendly constituents. To evaluate the potential application of these DESs, liquid-liquid extraction was performed to recover the typical biofuel fermentation products including acetone, ethanol, n-butanol, and isopentanol from aqueous solutions. High distribution coefficients, selectivity, and recovery rates for acetone, n-butanol, and isopentanol were achieved with the thymol: 2,6-dimethoxyphenol DESs. Moreover, molecular dynamic simulations were conducted to investigate the DES molecular interactions and formation mechanism. This work demonstrates the potential of lignin derived hydrophobic DESs for applications as sustainable extraction media.

Original languageEnglish
Article number135808
JournalJournal of Cleaner Production
Volume388
DOIs
StatePublished - Feb 15 2023

Bibliographical note

Publisher Copyright:
© 2022 Elsevier Ltd

Keywords

  • Biofuel
  • Green solvent
  • Liquid-liquid extraction
  • Molecular simulations

ASJC Scopus subject areas

  • General Environmental Science
  • Industrial and Manufacturing Engineering
  • Renewable Energy, Sustainability and the Environment
  • Strategy and Management

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