Localization length scales of triplet excitons in singlet fission materials

Sam L. Bayliss, Karl J. Thorley, John E. Anthony, Hélène Bouchiat, Neil C. Greenham, Alexei D. Chepelianskii

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

We measure the dielectric confinement length scales of triplet excitons in organic semiconductors by jointly measuring their microwave-domain electric and magnetic susceptibilities. We apply this technique to characterize triplet excitons in two singlet fission materials with distinct solid-state packing and correlate the extracted localization length scales with the role of the excitonic environment. By using the magnetic susceptibility simultaneously determined through our experiments, we compare the independently extracted dielectric and spin-spin localization length scales, highlighting the role of local anisotropy on the properties of excitonic triplet states.

Original languageEnglish
Article number115432
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume92
Issue number11
DOIs
StatePublished - Sep 21 2015

Bibliographical note

Publisher Copyright:
© 2015 American Physical Society.

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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