MAPbBr3nanocrystals from aqueous solution for poly(methyl methacrylate)-MAPbBr3nanocrystal films with compression-resistant photoluminescence

Xiaobing Tang; Yulin Zhang; Nadeesha Lakmali Kothalawala; Xiyu Wen; Doo Young Kim; Fuqian Yang

doi:10.1088/1361-6528/ac59e8

MAPbBr₃nanocrystals from aqueous solution for poly(methyl methacrylate)-MAPbBr₃nanocrystal films with compression-resistant photoluminescence

Xiaobing Tang
, Yulin Zhang
, Nadeesha Lakmali Kothalawala
, Xiyu Wen
, Doo Young Kim
, Fuqian Yang

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

In this work, we develop an environmental-friendly approach to produce organic-inorganic hybrid MAPbBr3 (MA = CH3NH3) perovskite nanocrystals (PeNCs) and PMMA-MAPbBr3 NC films with excellent compression-resistant PL characteristics. Deionized water is used as the solvent to synthesize MAPbBr3 powder instead of conventionally-used hazardous organic solvents. The MAPbBr3 PeNCs derived from the MAPbBr3 powder exhibit a high photoluminescence quantum yield (PLQY) of 93.86%. Poly(methyl methacrylate) (PMMA)-MAPbBr3 NC films made from the MAPbBr3 PeNCs retain 1/497% and 1/491% of initial PL intensity after 720 h aging in ambient environment at 50 °C and 70 °C, respectively. The PMMA-MAPbBr3 NC films also exhibit compression-resistant photoluminescent characteristics in contrast to the PMMA-CsPbBr3 NC films under a compressive stress of 1.6 MPa. The PMMA-MAPbBr3 NC film integrated with a red emissive film and a blue light emitting source achieves an LCD backlight of 1/4114% color gamut of National Television System Committee (NTSC) 1953 standard.

Original language	English
Article number	235605
Journal	Nanotechnology
Volume	33
Issue number	23
DOIs	https://doi.org/10.1088/1361-6528/ac59e8
State	Published - Jun 4 2022

Bibliographical note

Publisher Copyright:
© 2022 IOP Publishing Ltd.

Funding

FY is grateful for the support by the NSF through the grant CMMI-1854554, monitored by Drs Khershed Cooper and Thomas Francis Kuech, and CBET- 2018411 monitored by Dr Nora F Savage.

Funders	Funder number
National Science Foundation Arctic Social Science Program	CBET- 2018411, CMMI-1854554

Keywords

compression-resistant backlight films
deionized water
display
organic-inorganic hybrid perovskite nanocrystals

ASJC Scopus subject areas

Bioengineering
General Chemistry
General Materials Science
Mechanics of Materials
Mechanical Engineering
Electrical and Electronic Engineering

Access to Document

10.1088/1361-6528/ac59e8

Cite this

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title = "MAPbBr3nanocrystals from aqueous solution for poly(methyl methacrylate)-MAPbBr3nanocrystal films with compression-resistant photoluminescence",

abstract = "In this work, we develop an environmental-friendly approach to produce organic-inorganic hybrid MAPbBr3 (MA = CH3NH3) perovskite nanocrystals (PeNCs) and PMMA-MAPbBr3 NC films with excellent compression-resistant PL characteristics. Deionized water is used as the solvent to synthesize MAPbBr3 powder instead of conventionally-used hazardous organic solvents. The MAPbBr3 PeNCs derived from the MAPbBr3 powder exhibit a high photoluminescence quantum yield (PLQY) of 93.86\%. Poly(methyl methacrylate) (PMMA)-MAPbBr3 NC films made from the MAPbBr3 PeNCs retain 1/497\% and 1/491\% of initial PL intensity after 720 h aging in ambient environment at 50 °C and 70 °C, respectively. The PMMA-MAPbBr3 NC films also exhibit compression-resistant photoluminescent characteristics in contrast to the PMMA-CsPbBr3 NC films under a compressive stress of 1.6 MPa. The PMMA-MAPbBr3 NC film integrated with a red emissive film and a blue light emitting source achieves an LCD backlight of 1/4114\% color gamut of National Television System Committee (NTSC) 1953 standard.",

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author = "Xiaobing Tang and Yulin Zhang and Kothalawala, \{Nadeesha Lakmali\} and Xiyu Wen and Kim, \{Doo Young\} and Fuqian Yang",

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AU - Tang, Xiaobing

AU - Zhang, Yulin

AU - Kothalawala, Nadeesha Lakmali

AU - Wen, Xiyu

AU - Kim, Doo Young

AU - Yang, Fuqian

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AB - In this work, we develop an environmental-friendly approach to produce organic-inorganic hybrid MAPbBr3 (MA = CH3NH3) perovskite nanocrystals (PeNCs) and PMMA-MAPbBr3 NC films with excellent compression-resistant PL characteristics. Deionized water is used as the solvent to synthesize MAPbBr3 powder instead of conventionally-used hazardous organic solvents. The MAPbBr3 PeNCs derived from the MAPbBr3 powder exhibit a high photoluminescence quantum yield (PLQY) of 93.86%. Poly(methyl methacrylate) (PMMA)-MAPbBr3 NC films made from the MAPbBr3 PeNCs retain 1/497% and 1/491% of initial PL intensity after 720 h aging in ambient environment at 50 °C and 70 °C, respectively. The PMMA-MAPbBr3 NC films also exhibit compression-resistant photoluminescent characteristics in contrast to the PMMA-CsPbBr3 NC films under a compressive stress of 1.6 MPa. The PMMA-MAPbBr3 NC film integrated with a red emissive film and a blue light emitting source achieves an LCD backlight of 1/4114% color gamut of National Television System Committee (NTSC) 1953 standard.

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