Metastable interwoven mesoporous metal-organic frameworks

Yabing He; Zhiyong Guo; Shengchang Xiang; Zhangjing Zhang; Wei Zhou; Frank R. Fronczek; Sean Parkin; Stephen T. Hyde; Michael O'Keeffe; Banglin Chen

doi:10.1021/ic401870e

Metastable interwoven mesoporous metal-organic frameworks

Yabing He, Zhiyong Guo, Shengchang Xiang, Zhangjing Zhang, Wei Zhou, Frank R. Fronczek, Sean Parkin, Stephen T. Hyde, Michael O'Keeffe, Banglin Chen

Chemistry

Research output: Contribution to journal › Article › peer-review

65 Scopus citations

Abstract

Three isostructural interwoven 3,4-connected mesoporous metal-organic frameworks of pto-a topology (UTSA-28-Cu, UTSA-28-Zn, and UTSA-28-Mn) were synthesized and structurally characterized. Because of their metastable nature, their gas sorption properties are highly dependent on the metal ions and activation profiles. The most stable, UTSA-28a-Cu, exhibits promising gas storage and separation capacities.

Original language	English
Pages (from-to)	11580-11584
Number of pages	5
Journal	Inorganic Chemistry
Volume	52
Issue number	19
DOIs	https://doi.org/10.1021/ic401870e
State	Published - Oct 7 2013

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic401870e

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title = "Metastable interwoven mesoporous metal-organic frameworks",

abstract = "Three isostructural interwoven 3,4-connected mesoporous metal-organic frameworks of pto-a topology (UTSA-28-Cu, UTSA-28-Zn, and UTSA-28-Mn) were synthesized and structurally characterized. Because of their metastable nature, their gas sorption properties are highly dependent on the metal ions and activation profiles. The most stable, UTSA-28a-Cu, exhibits promising gas storage and separation capacities.",

author = "Yabing He and Zhiyong Guo and Shengchang Xiang and Zhangjing Zhang and Wei Zhou and Fronczek, {Frank R.} and Sean Parkin and Hyde, {Stephen T.} and Michael O'Keeffe and Banglin Chen",

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doi = "10.1021/ic401870e",

language = "English",

volume = "52",

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T1 - Metastable interwoven mesoporous metal-organic frameworks

AU - He, Yabing

AU - Guo, Zhiyong

AU - Xiang, Shengchang

AU - Zhang, Zhangjing

AU - Zhou, Wei

AU - Fronczek, Frank R.

AU - Parkin, Sean

AU - Hyde, Stephen T.

AU - O'Keeffe, Michael

AU - Chen, Banglin

PY - 2013/10/7

Y1 - 2013/10/7

N2 - Three isostructural interwoven 3,4-connected mesoporous metal-organic frameworks of pto-a topology (UTSA-28-Cu, UTSA-28-Zn, and UTSA-28-Mn) were synthesized and structurally characterized. Because of their metastable nature, their gas sorption properties are highly dependent on the metal ions and activation profiles. The most stable, UTSA-28a-Cu, exhibits promising gas storage and separation capacities.

AB - Three isostructural interwoven 3,4-connected mesoporous metal-organic frameworks of pto-a topology (UTSA-28-Cu, UTSA-28-Zn, and UTSA-28-Mn) were synthesized and structurally characterized. Because of their metastable nature, their gas sorption properties are highly dependent on the metal ions and activation profiles. The most stable, UTSA-28a-Cu, exhibits promising gas storage and separation capacities.

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VL - 52

SP - 11580

EP - 11584

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 19

ER -

Metastable interwoven mesoporous metal-organic frameworks

Abstract

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