Monomeric Base-Stabilized Phosphino- and Arsinoalanes

David A. Atwood; Leopoldo Contreras; Alan H. Cowley; Richard A. Jones; Miguel A. Mardones

doi:10.1021/om00025a008

Monomeric Base-Stabilized Phosphino- and Arsinoalanes

David A. Atwood, Leopoldo Contreras, Alan H. Cowley, Richard A. Jones, Miguel A. Mardones

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31 Scopus citations

Abstract

The first base-stabilized phosphino- and arsinoalane monomers, H₂AlEMes₂·NMe₃ (Mes = mesityl; 1, E = P; 2, E = As) have been prepared. Thermolysis at 95°C converts 1 to the trimer [H₂AlPMes₂]₃ (3); further heating at 125 °C results in the formation of Mes₂pH and aluminum metal.

Original language	English
Pages (from-to)	17-18
Number of pages	2
Journal	Organometallics
Volume	12
Issue number	1
DOIs	https://doi.org/10.1021/om00025a008
State	Published - 1993

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om00025a008

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title = "Monomeric Base-Stabilized Phosphino- and Arsinoalanes",

abstract = "The first base-stabilized phosphino- and arsinoalane monomers, H2AlEMes2·NMe3 (Mes = mesityl; 1, E = P; 2, E = As) have been prepared. Thermolysis at 95°C converts 1 to the trimer [H2AlPMes2]3 (3); further heating at 125 °C results in the formation of Mes2pH and aluminum metal.",

author = "Atwood, {David A.} and Leopoldo Contreras and Cowley, {Alan H.} and Jones, {Richard A.} and Mardones, {Miguel A.}",

year = "1993",

doi = "10.1021/om00025a008",

language = "English",

volume = "12",

pages = "17--18",

number = "1",

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T1 - Monomeric Base-Stabilized Phosphino- and Arsinoalanes

AU - Atwood, David A.

AU - Contreras, Leopoldo

AU - Cowley, Alan H.

AU - Jones, Richard A.

AU - Mardones, Miguel A.

PY - 1993

Y1 - 1993

N2 - The first base-stabilized phosphino- and arsinoalane monomers, H2AlEMes2·NMe3 (Mes = mesityl; 1, E = P; 2, E = As) have been prepared. Thermolysis at 95°C converts 1 to the trimer [H2AlPMes2]3 (3); further heating at 125 °C results in the formation of Mes2pH and aluminum metal.

AB - The first base-stabilized phosphino- and arsinoalane monomers, H2AlEMes2·NMe3 (Mes = mesityl; 1, E = P; 2, E = As) have been prepared. Thermolysis at 95°C converts 1 to the trimer [H2AlPMes2]3 (3); further heating at 125 °C results in the formation of Mes2pH and aluminum metal.

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U2 - 10.1021/om00025a008

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IS - 1

ER -

Monomeric Base-Stabilized Phosphino- and Arsinoalanes

Abstract

ASJC Scopus subject areas

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