Monomeric Group 13 compounds with bidentate (N, O) ligands

Michael S. Hill; Aaron R. Hutchison; Timothy S. Keizer; Sean Parkin; Michael A. Vanaelstyn; David A. Atwood

doi:10.1016/S0022-328X(01)00738-0

Monomeric Group 13 compounds with bidentate (N, O) ligands

Michael S. Hill, Aaron R. Hutchison, Timothy S. Keizer, Sean Parkin, Michael A. Vanaelstyn, David A. Atwood

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

The bidentate ligand, Sal(^tBu)H, is prepared by the condensation of one equivalent of a bulky amine with 3,-5-di-tert-butylsalicylaldehyde. When one equivalent of Sal(^tBu)H is added to MR₃ or AlMe₂Cl, compounds are btained which have the general form: [Sal(^tBu)MR₂] (with M/R combinations, Al/Me (1), Al/Et (3), Ga/Et (4) and In/Et (5)) and Sal(^tBu)AlMeCl (2). The compounds are characterized by melting point, elemental analyses, IR, ¹H-NMR, and in the case of 2 and 3 by single-crystal X-ray analysis.

Original language	English
Pages (from-to)	71-75
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	628
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(01)00738-0
State	Published - May 15 2001

Bibliographical note

Funding Information:
This work was supported by the National Science Foundation NSF-CAREER award (CHE 9625376) and the donors of the Petroleum Research Fund (Grant 31901-AC3), administered by the American Chemical Society. NMR instruments used in this research were obtained with funds from the CRIF program of the National Science Foundation (CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky.

Funding

This work was supported by the National Science Foundation NSF-CAREER award (CHE 9625376) and the donors of the Petroleum Research Fund (Grant 31901-AC3), administered by the American Chemical Society. NMR instruments used in this research were obtained with funds from the CRIF program of the National Science Foundation (CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky.

Funders	Funder number
National Science Foundation (NSF)	CHE 9625376
American Chemical Society	CHE 997841
American Chemical Society Petroleum Research Fund	31901-AC3
University of Kentucky

Keywords

Aluminum
Chelate
Gallium

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(01)00738-0

Cite this

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title = "Monomeric Group 13 compounds with bidentate (N, O) ligands",

abstract = "The bidentate ligand, Sal(tBu)H, is prepared by the condensation of one equivalent of a bulky amine with 3,-5-di-tert-butylsalicylaldehyde. When one equivalent of Sal(tBu)H is added to MR3 or AlMe2Cl, compounds are btained which have the general form: [Sal(tBu)MR2] (with M/R combinations, Al/Me (1), Al/Et (3), Ga/Et (4) and In/Et (5)) and Sal(tBu)AlMeCl (2). The compounds are characterized by melting point, elemental analyses, IR, 1H-NMR, and in the case of 2 and 3 by single-crystal X-ray analysis.",

keywords = "Aluminum, Chelate, Gallium",

author = "Hill, {Michael S.} and Hutchison, {Aaron R.} and Keizer, {Timothy S.} and Sean Parkin and Vanaelstyn, {Michael A.} and Atwood, {David A.}",

note = "Funding Information: This work was supported by the National Science Foundation NSF-CAREER award (CHE 9625376) and the donors of the Petroleum Research Fund (Grant 31901-AC3), administered by the American Chemical Society. NMR instruments used in this research were obtained with funds from the CRIF program of the National Science Foundation (CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky.",

year = "2001",

month = may,

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doi = "10.1016/S0022-328X(01)00738-0",

language = "English",

volume = "628",

pages = "71--75",

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TY - JOUR

T1 - Monomeric Group 13 compounds with bidentate (N, O) ligands

AU - Hill, Michael S.

AU - Hutchison, Aaron R.

AU - Keizer, Timothy S.

AU - Parkin, Sean

AU - Vanaelstyn, Michael A.

AU - Atwood, David A.

N1 - Funding Information: This work was supported by the National Science Foundation NSF-CAREER award (CHE 9625376) and the donors of the Petroleum Research Fund (Grant 31901-AC3), administered by the American Chemical Society. NMR instruments used in this research were obtained with funds from the CRIF program of the National Science Foundation (CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky.

PY - 2001/5/15

Y1 - 2001/5/15

N2 - The bidentate ligand, Sal(tBu)H, is prepared by the condensation of one equivalent of a bulky amine with 3,-5-di-tert-butylsalicylaldehyde. When one equivalent of Sal(tBu)H is added to MR3 or AlMe2Cl, compounds are btained which have the general form: [Sal(tBu)MR2] (with M/R combinations, Al/Me (1), Al/Et (3), Ga/Et (4) and In/Et (5)) and Sal(tBu)AlMeCl (2). The compounds are characterized by melting point, elemental analyses, IR, 1H-NMR, and in the case of 2 and 3 by single-crystal X-ray analysis.

AB - The bidentate ligand, Sal(tBu)H, is prepared by the condensation of one equivalent of a bulky amine with 3,-5-di-tert-butylsalicylaldehyde. When one equivalent of Sal(tBu)H is added to MR3 or AlMe2Cl, compounds are btained which have the general form: [Sal(tBu)MR2] (with M/R combinations, Al/Me (1), Al/Et (3), Ga/Et (4) and In/Et (5)) and Sal(tBu)AlMeCl (2). The compounds are characterized by melting point, elemental analyses, IR, 1H-NMR, and in the case of 2 and 3 by single-crystal X-ray analysis.

KW - Aluminum

KW - Chelate

KW - Gallium

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DO - 10.1016/S0022-328X(01)00738-0

M3 - Article

AN - SCOPUS:0002580076

SN - 0022-328X

VL - 628

SP - 71

EP - 75

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Monomeric Group 13 compounds with bidentate (N, O) ligands

Abstract

Bibliographical note

Funding

Keywords

ASJC Scopus subject areas

Access to Document

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