Naturally Occurring Radioactive Materials in Coals and Coal Combustion Residuals in the United States

Nancy E. Lauer, James C. Hower, Heileen Hsu-Kim, Ross K. Taggart, Avner Vengosh

Research output: Contribution to journalArticlepeer-review

66 Scopus citations

Abstract

The distribution and enrichment of naturally occurring radioactive materials (NORM) in coal combustion residuals (CCRs) from different coal source basins have not been fully characterized in the United States. Here we provide a systematic analysis of the occurrence of NORM (232Th, 228Ra, 238U, 226Ra, and 210Pb) in coals and associated CCRs from the Illinois, Appalachian, and Powder River Basins. Illinois CCRs had the highest total Ra (228Ra + 226Ra = 297 ± 46 Bq/kg) and the lowest 228Ra/226Ra activity ratio (0.31 ± 0.09), followed by Appalachian CCRs (283 ± 34 Bq/kg; 0.67 ± 0.09), and Powder River CCRs (213 ± 21 Bq/kg; 0.79 ± 0.10). Total Ra and 228Ra/226Ra variations in CCRs correspond to the U and Th concentrations and ash contents of their feed coals, and we show that these relationships can be used to predict total NORM concentrations in CCRs. We observed differential NORM volatility during combustion that results in 210Pb enrichment and 210Pb/226Ra ratios greater than 1 in most fly-ash samples. Overall, total NORM activities in CCRs are 7-10- and 3-5-fold higher than NORM activities in parent coals and average U.S. soil, respectively. This study lays the groundwork for future research related to the environmental and human health implications of CCR disposal and accidental release to the environment in the context of this elevated radioactivity.

Original languageEnglish
Pages (from-to)11227-11233
Number of pages7
JournalEnvironmental Science and Technology
Volume49
Issue number18
DOIs
StatePublished - Sep 15 2015

Bibliographical note

Publisher Copyright:
© 2015 American Chemical Society.

ASJC Scopus subject areas

  • General Chemistry
  • Environmental Chemistry

Fingerprint

Dive into the research topics of 'Naturally Occurring Radioactive Materials in Coals and Coal Combustion Residuals in the United States'. Together they form a unique fingerprint.

Cite this