TY - JOUR
T1 - Nitration of benzothioxanthene
T2 - Towards a new class of dyes with versatile photophysical properties
AU - Andrés Castán, José María
AU - Abad Galán, Laura
AU - Li, Shi
AU - Dalinot, Clément
AU - Simón Marqués, Pablo
AU - Allain, Magali
AU - Risko, Chad
AU - Monnereau, Cyrille
AU - Maury, Olivier
AU - Blanchard, Philippe
AU - Cabanetos, Clément
N1 - Publisher Copyright:
This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
PY - 2020
Y1 - 2020
N2 - The selective mono-nitration of benzothioxanthane (BTXI) is demonstrated herein. This leap opens doors to a wide range of chemical reactions since the nitro compound was successfully reduced to a primary amine that was, in turn, converted into an azide. Beyond this chemical achievement, this new series of functionalized BTXI was fully characterized, including from a photophysical point of view, expanding the scope of this promising rylene to build a new electroactive π-conjugated platform for electronic organic purposes.
AB - The selective mono-nitration of benzothioxanthane (BTXI) is demonstrated herein. This leap opens doors to a wide range of chemical reactions since the nitro compound was successfully reduced to a primary amine that was, in turn, converted into an azide. Beyond this chemical achievement, this new series of functionalized BTXI was fully characterized, including from a photophysical point of view, expanding the scope of this promising rylene to build a new electroactive π-conjugated platform for electronic organic purposes.
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U2 - 10.1039/c9nj05804d
DO - 10.1039/c9nj05804d
M3 - Article
AN - SCOPUS:85078429326
SN - 1144-0546
VL - 44
SP - 900
EP - 905
JO - New Journal of Chemistry
JF - New Journal of Chemistry
IS - 3
ER -