Novel catalyst use in glycerin dehydration chemistry

Wesley A. Whipple, Jeffrey Seay

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

Traditionally in biodiesel production vegetable oils such as soy, canola, or corn oil are reacted with a mono-alcohol in order to cleave fatty acids from a glycerol backbone. Glycerol is produced as a co-product from this reaction and has lead to a glut in the glycerol market. In order to further increase the usefulness of this co-product, a catalytic gas dehydration of pure glycerol is performed in order to produce acrolein which is a more valuable precursor chemical in the production of acrylic acid and other specialty chemicals. There are many catalysts that can be used in this dehydration process; typically phosphoric acid is used but this has led to problems with coking and fouling due to its overly acidic nature. To alleviate this issue the catalyst sodium dihydrogen phosphate is used.

Original languageEnglish
Title of host publicationSustainable Engineering Forum
Subtitle of host publicationCore Programming Topic at the 2011 AIChE Annual Meeting
Pages812
Number of pages1
StatePublished - 2011
EventSustainable Engineering Forum: Core Programming Topic at the 2011 AIChE Annual Meeting - Minneapolis, United States
Duration: Oct 16 2011Oct 21 2011

Publication series

NameSustainable Engineering Forum: Core Programming Topic at the 2011 AIChE Annual Meeting
Volume2

Conference

ConferenceSustainable Engineering Forum: Core Programming Topic at the 2011 AIChE Annual Meeting
Country/TerritoryUnited States
CityMinneapolis
Period10/16/1110/21/11

Bibliographical note

Publisher Copyright:
© 2011 by AIChE. All rights reserved.

ASJC Scopus subject areas

  • Chemical Health and Safety
  • Safety, Risk, Reliability and Quality
  • Safety Research

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