Novel Cross‐Conjugated Compounds Derived from Tetraethynylethene

Armen M. Boldi, John Anthony, Carolyn B. Knobler, François Diederich

Research output: Contribution to journalArticlepeer-review

35 Scopus citations

Abstract

The oxidative coupling of a tetraethynylethene derivative with a single free ethynyl function afforded a silyl‐protected derivative la, which was characterized by an X‐ray structure analysis. It was protodesilylated to the first C20H6 isomer 1b. Evidence of the expanded π‐electron delocalization in the new cross‐conjugated system comes from UV/VIS spectroscopy. (Figure Presented.)

Original languageEnglish
Pages (from-to)1240-1242
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume31
Issue number9
DOIs
StatePublished - Sep 1992

ASJC Scopus subject areas

  • Catalysis
  • Chemistry (all)

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