One- and three-dimensional octacyanometalate(IV) networks constructed via a building block approach: {[trans-NiII(tn)2(OH 2)][trans-NiII(μ-NC)2(tn) 2][(μ-NC)3MIV(CN)5]•6H 2O} (MIV = Mo, W)

Jeffrey R. Withers; Chad Ruschman; Sean Parkin; Stephen M. Holmes

doi:10.1016/j.poly.2005.06.052

One- and three-dimensional octacyanometalate(IV) networks constructed via a building block approach: {[trans-Ni^II(tn)₂(OH ₂)][trans-Ni^II(μ-NC)₂(tn) ₂][(μ-NC)₃M^IV(CN)₅]•6H ₂O} (M^IV = Mo, W)

Jeffrey R. Withers, Chad Ruschman, Sean Parkin, Stephen M. Holmes

Chemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Treatment of [Ni^II(tn)₃][OTs]₂ or aqueous solutions containing nickel(II) p-toluenesulfonate and 1,3-propanediamine (tn) with aqueous K₄M^IV(CN)₈ • 2H₂O (M^IV = Mo, W) affords one-dimensional chains of {[trans-Ni ^II(tn)₂(OH₂)][trans-Ni^II(tn) ₂][(μ-NC)₃M^IV(CN)₅] • 6H₂O} stoichiometry (M^IV = Mo, 2; W, 3). An additional three-dimensional network, Cs₄[Cu^II(OH₂) ₄]₂[Cu^II(NH₃)]₄[Mo ^IV(CN)₈]₄ • 2H₂O (4), is obtained by treating aqueous solutions of Cs₃Mo^V(CN) ₈ with CuCl₂ • 2H₂O in concentrated ammonia. Each network has been characterized via structural and magnetic methods. The distorted square anitprismatic MIV(CN)84- centers are diamagnetic and the paramagnetism of each network originates from the Ni^II and Cu^II centers present.

Original language	English
Pages (from-to)	1845-1854
Number of pages	10
Journal	Polyhedron
Volume	24
Issue number	14
DOIs	https://doi.org/10.1016/j.poly.2005.06.052
State	Published - Oct 3 2005

Bibliographical note

Funding Information:
Acknowledgment is made to the Donors of the American Chemical Society Petroleum Research Fund (PRF-38388-G3), the National Science Foundation Research Experience for Undergraduates (CHE-0097668), and the University of Kentucky Summer Faculty Research Fellowship programs for partial financial support. S.M.H. is also grateful for access to the Frederick Seitz Materials Research Laboratory magnetometer facility at the University of Illinois at Urbana-Champaign.

Keywords

Cyanide networks
Octacyanometalates

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.poly.2005.06.052

Cite this

@article{1bee81154fed482aaf094324443aea6c,

title = "One- and three-dimensional octacyanometalate(IV) networks constructed via a building block approach: {[trans-NiII(tn)2(OH 2)][trans-NiII(μ-NC)2(tn) 2][(μ-NC)3MIV(CN)5]•6H 2O} (MIV = Mo, W)",

abstract = "Treatment of [NiII(tn)3][OTs]2 or aqueous solutions containing nickel(II) p-toluenesulfonate and 1,3-propanediamine (tn) with aqueous K4MIV(CN)8 • 2H2O (MIV = Mo, W) affords one-dimensional chains of {[trans-Ni II(tn)2(OH2)][trans-NiII(tn) 2][(μ-NC)3MIV(CN)5] • 6H2O} stoichiometry (MIV = Mo, 2; W, 3). An additional three-dimensional network, Cs4[CuII(OH2) 4]2[CuII(NH3)]4[Mo IV(CN)8]4 • 2H2O (4), is obtained by treating aqueous solutions of Cs3MoV(CN) 8 with CuCl2 • 2H2O in concentrated ammonia. Each network has been characterized via structural and magnetic methods. The distorted square anitprismatic MIV(CN)84- centers are diamagnetic and the paramagnetism of each network originates from the NiII and CuII centers present.",

keywords = "Cyanide networks, Octacyanometalates",

author = "Withers, {Jeffrey R.} and Chad Ruschman and Sean Parkin and Holmes, {Stephen M.}",

note = "Funding Information: Acknowledgment is made to the Donors of the American Chemical Society Petroleum Research Fund (PRF-38388-G3), the National Science Foundation Research Experience for Undergraduates (CHE-0097668), and the University of Kentucky Summer Faculty Research Fellowship programs for partial financial support. S.M.H. is also grateful for access to the Frederick Seitz Materials Research Laboratory magnetometer facility at the University of Illinois at Urbana-Champaign. ",

year = "2005",

month = oct,

day = "3",

doi = "10.1016/j.poly.2005.06.052",

language = "English",

volume = "24",

pages = "1845--1854",

number = "14",

}

One- and three-dimensional octacyanometalate(IV) networks constructed via a building block approach: {[trans-Ni^II(tn)₂(OH ₂)][trans-Ni^II(μ-NC)₂(tn) ₂][(μ-NC)₃M^IV(CN)₅]•6H ₂O} (M^IV = Mo, W). / Withers, Jeffrey R.; Ruschman, Chad; Parkin, Sean et al.
In: Polyhedron, Vol. 24, No. 14, 03.10.2005, p. 1845-1854.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - One- and three-dimensional octacyanometalate(IV) networks constructed via a building block approach

T2 - {[trans-NiII(tn)2(OH 2)][trans-NiII(μ-NC)2(tn) 2][(μ-NC)3MIV(CN)5]•6H 2O} (MIV = Mo, W)

AU - Withers, Jeffrey R.

AU - Ruschman, Chad

AU - Parkin, Sean

AU - Holmes, Stephen M.

N1 - Funding Information: Acknowledgment is made to the Donors of the American Chemical Society Petroleum Research Fund (PRF-38388-G3), the National Science Foundation Research Experience for Undergraduates (CHE-0097668), and the University of Kentucky Summer Faculty Research Fellowship programs for partial financial support. S.M.H. is also grateful for access to the Frederick Seitz Materials Research Laboratory magnetometer facility at the University of Illinois at Urbana-Champaign.

PY - 2005/10/3

Y1 - 2005/10/3

N2 - Treatment of [NiII(tn)3][OTs]2 or aqueous solutions containing nickel(II) p-toluenesulfonate and 1,3-propanediamine (tn) with aqueous K4MIV(CN)8 • 2H2O (MIV = Mo, W) affords one-dimensional chains of {[trans-Ni II(tn)2(OH2)][trans-NiII(tn) 2][(μ-NC)3MIV(CN)5] • 6H2O} stoichiometry (MIV = Mo, 2; W, 3). An additional three-dimensional network, Cs4[CuII(OH2) 4]2[CuII(NH3)]4[Mo IV(CN)8]4 • 2H2O (4), is obtained by treating aqueous solutions of Cs3MoV(CN) 8 with CuCl2 • 2H2O in concentrated ammonia. Each network has been characterized via structural and magnetic methods. The distorted square anitprismatic MIV(CN)84- centers are diamagnetic and the paramagnetism of each network originates from the NiII and CuII centers present.

AB - Treatment of [NiII(tn)3][OTs]2 or aqueous solutions containing nickel(II) p-toluenesulfonate and 1,3-propanediamine (tn) with aqueous K4MIV(CN)8 • 2H2O (MIV = Mo, W) affords one-dimensional chains of {[trans-Ni II(tn)2(OH2)][trans-NiII(tn) 2][(μ-NC)3MIV(CN)5] • 6H2O} stoichiometry (MIV = Mo, 2; W, 3). An additional three-dimensional network, Cs4[CuII(OH2) 4]2[CuII(NH3)]4[Mo IV(CN)8]4 • 2H2O (4), is obtained by treating aqueous solutions of Cs3MoV(CN) 8 with CuCl2 • 2H2O in concentrated ammonia. Each network has been characterized via structural and magnetic methods. The distorted square anitprismatic MIV(CN)84- centers are diamagnetic and the paramagnetism of each network originates from the NiII and CuII centers present.

KW - Cyanide networks

KW - Octacyanometalates

UR - http://www.scopus.com/inward/record.url?scp=24644485388&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=24644485388&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2005.06.052

DO - 10.1016/j.poly.2005.06.052

M3 - Article

AN - SCOPUS:24644485388

SN - 0277-5387

VL - 24

SP - 1845

EP - 1854

JO - Polyhedron

JF - Polyhedron

IS - 14

ER -