Oxidation of aryl alkyl ketones to α-acyloxy, α-(camphorsulfonyloxy), or α-hydroxy derivatives using manganese(iii) acetate in combination with carboxylic acids or (1s)-(+)-10-camphorsulfonic acid

Ayhan S. Demir; Nurettin Camkerten; Hulya Akgun; Cihangir Tanyeli; Ali S. Mahasneh; David S. Watt

doi:10.1080/00397919008053170

Oxidation of aryl alkyl ketones to α-acyloxy, α-(camphorsulfonyloxy), or α-hydroxy derivatives using manganese(iii) acetate in combination with carboxylic acids or (1s)-(+)-10-camphorsulfonic acid

Ayhan S. Demir, Nurettin Camkerten, Hulya Akgun, Cihangir Tanyeli, Ali S. Mahasneh, David S. Watt

Molecular and Cellular Biochemistry

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

The a-oxidation of aryl alkyl ketones using manganese(III) acetate in the presence of various carboxylic acids and (1S)-(+)-10-camphorsulfonic acid provided a convenient synthesis of α-acyloxy, a-(10-camphorsulfonyloxy), and a-hydroxy derivatives in good yield.

Original language	English
Pages (from-to)	2279-2289
Number of pages	11
Journal	Synthetic Communications
Volume	20
Issue number	15
DOIs	https://doi.org/10.1080/00397919008053170
State	Published - Aug 1 1990

Bibliographical note

Funding Information:
Health for generous financial support (GM 362561, NATO for travel grants (RG #0346/88) to D.S.W. and A.D., Degussa A.G. for a gift of chemicals, and the University of Kentucky for the purchase of Bond Issue Equipment.

Funding Information:
We thank the Middle-East Technical University for grant (No. AFP 89-01-03-04), the National Institutes of

ASJC Scopus subject areas

Organic Chemistry

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10.1080/00397919008053170

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Demir, A. S., Camkerten, N., Akgun, H., Tanyeli, C., Mahasneh, A. S., & Watt, D. S. (1990). Oxidation of aryl alkyl ketones to α-acyloxy, α-(camphorsulfonyloxy), or α-hydroxy derivatives using manganese(iii) acetate in combination with carboxylic acids or (1s)-(+)-10-camphorsulfonic acid. Synthetic Communications, 20(15), 2279-2289. https://doi.org/10.1080/00397919008053170

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title = "Oxidation of aryl alkyl ketones to α-acyloxy, α-(camphorsulfonyloxy), or α-hydroxy derivatives using manganese(iii) acetate in combination with carboxylic acids or (1s)-(+)-10-camphorsulfonic acid",

abstract = "The a-oxidation of aryl alkyl ketones using manganese(III) acetate in the presence of various carboxylic acids and (1S)-(+)-10-camphorsulfonic acid provided a convenient synthesis of α-acyloxy, a-(10-camphorsulfonyloxy), and a-hydroxy derivatives in good yield.",

author = "Demir, {Ayhan S.} and Nurettin Camkerten and Hulya Akgun and Cihangir Tanyeli and Mahasneh, {Ali S.} and Watt, {David S.}",

note = "Funding Information: Health for generous financial support (GM 362561, NATO for travel grants (RG #0346/88) to D.S.W. and A.D., Degussa A.G. for a gift of chemicals, and the University of Kentucky for the purchase of Bond Issue Equipment. Funding Information: We thank the Middle-East Technical University for grant (No. AFP 89-01-03-04), the National Institutes of",

year = "1990",

month = aug,

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doi = "10.1080/00397919008053170",

language = "English",

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Demir, AS, Camkerten, N, Akgun, H, Tanyeli, C, Mahasneh, AS & Watt, DS 1990, 'Oxidation of aryl alkyl ketones to α-acyloxy, α-(camphorsulfonyloxy), or α-hydroxy derivatives using manganese(iii) acetate in combination with carboxylic acids or (1s)-(+)-10-camphorsulfonic acid', Synthetic Communications, vol. 20, no. 15, pp. 2279-2289. https://doi.org/10.1080/00397919008053170

Oxidation of aryl alkyl ketones to α-acyloxy, α-(camphorsulfonyloxy), or α-hydroxy derivatives using manganese(iii) acetate in combination with carboxylic acids or (1s)-(+)-10-camphorsulfonic acid. / Demir, Ayhan S.; Camkerten, Nurettin; Akgun, Hulya et al.

In: Synthetic Communications, Vol. 20, No. 15, 01.08.1990, p. 2279-2289.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Oxidation of aryl alkyl ketones to α-acyloxy, α-(camphorsulfonyloxy), or α-hydroxy derivatives using manganese(iii) acetate in combination with carboxylic acids or (1s)-(+)-10-camphorsulfonic acid

AU - Demir, Ayhan S.

AU - Camkerten, Nurettin

AU - Akgun, Hulya

AU - Tanyeli, Cihangir

AU - Mahasneh, Ali S.

AU - Watt, David S.

N1 - Funding Information: Health for generous financial support (GM 362561, NATO for travel grants (RG #0346/88) to D.S.W. and A.D., Degussa A.G. for a gift of chemicals, and the University of Kentucky for the purchase of Bond Issue Equipment. Funding Information: We thank the Middle-East Technical University for grant (No. AFP 89-01-03-04), the National Institutes of

PY - 1990/8/1

Y1 - 1990/8/1

N2 - The a-oxidation of aryl alkyl ketones using manganese(III) acetate in the presence of various carboxylic acids and (1S)-(+)-10-camphorsulfonic acid provided a convenient synthesis of α-acyloxy, a-(10-camphorsulfonyloxy), and a-hydroxy derivatives in good yield.

AB - The a-oxidation of aryl alkyl ketones using manganese(III) acetate in the presence of various carboxylic acids and (1S)-(+)-10-camphorsulfonic acid provided a convenient synthesis of α-acyloxy, a-(10-camphorsulfonyloxy), and a-hydroxy derivatives in good yield.

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Oxidation of aryl alkyl ketones to α-acyloxy, α-(camphorsulfonyloxy), or α-hydroxy derivatives using manganese(iii) acetate in combination with carboxylic acids or (1s)-(+)-10-camphorsulfonic acid

Abstract

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