Oxidative addition reactions and reverse ylide formation involving macrocyclic (TMTAA, C22H22N4) complexes of germanium(II) and tin(II)

David A. Atwood; Vicki O. Atwood; Alan H. Cowley; Hala R. Gobran

doi:10.1016/S0277-5387(00)81485-0

Oxidative addition reactions and reverse ylide formation involving macrocyclic (TMTAA, C₂₂H₂₂N₄) complexes of germanium(II) and tin(II)

David A. Atwood, Vicki O. Atwood, Alan H. Cowley, Hala R. Gobran

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The germanium(II) and tin(II) macrocyclic complexes Ge(tmtaa) (1) and Sn(tmtaa) (2) (tmtaa = dibenzotetramethyltetraaza[14]annulene) undergo facile oxidative addition reactions and reverse ylide formation with MeI and C₆Fe₅I, respectively.

Original language	English
Pages (from-to)	2073-2074
Number of pages	2
Journal	Polyhedron
Volume	12
Issue number	16
DOIs	https://doi.org/10.1016/S0277-5387(00)81485-0
State	Published - Aug 1993

Bibliographical note

Funding Information:
Acknowledgements-We are grateful to the National Science Foundation (Grant CHE 9108228)a nd the Robert A. Welch Foundation for generousf inancial support.

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0277-5387(00)81485-0

Cite this

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title = "Oxidative addition reactions and reverse ylide formation involving macrocyclic (TMTAA, C22H22N4) complexes of germanium(II) and tin(II)",

abstract = "The germanium(II) and tin(II) macrocyclic complexes Ge(tmtaa) (1) and Sn(tmtaa) (2) (tmtaa = dibenzotetramethyltetraaza[14]annulene) undergo facile oxidative addition reactions and reverse ylide formation with MeI and C6Fe5I, respectively.",

author = "Atwood, {David A.} and Atwood, {Vicki O.} and Cowley, {Alan H.} and Gobran, {Hala R.}",

note = "Funding Information: Acknowledgements-We are grateful to the National Science Foundation (Grant CHE 9108228)a nd the Robert A. Welch Foundation for generousf inancial support.",

year = "1993",

month = aug,

doi = "10.1016/S0277-5387(00)81485-0",

language = "English",

volume = "12",

pages = "2073--2074",

number = "16",

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T1 - Oxidative addition reactions and reverse ylide formation involving macrocyclic (TMTAA, C22H22N4) complexes of germanium(II) and tin(II)

AU - Atwood, David A.

AU - Atwood, Vicki O.

AU - Cowley, Alan H.

AU - Gobran, Hala R.

N1 - Funding Information: Acknowledgements-We are grateful to the National Science Foundation (Grant CHE 9108228)a nd the Robert A. Welch Foundation for generousf inancial support.

PY - 1993/8

Y1 - 1993/8

N2 - The germanium(II) and tin(II) macrocyclic complexes Ge(tmtaa) (1) and Sn(tmtaa) (2) (tmtaa = dibenzotetramethyltetraaza[14]annulene) undergo facile oxidative addition reactions and reverse ylide formation with MeI and C6Fe5I, respectively.

AB - The germanium(II) and tin(II) macrocyclic complexes Ge(tmtaa) (1) and Sn(tmtaa) (2) (tmtaa = dibenzotetramethyltetraaza[14]annulene) undergo facile oxidative addition reactions and reverse ylide formation with MeI and C6Fe5I, respectively.

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JO - Polyhedron

JF - Polyhedron

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