TY - JOUR
T1 - Photoelectron spectroscopy and density functional theory of puckered ring structures of Group 13 metal-ethylenediamine
AU - Li, Shenggang
AU - Fuller, Jason F.
AU - Wang, Xu
AU - Sohnlein, Bradford R.
AU - Bhowmik, Paragranjita
AU - Yang, Dong Sheng
PY - 2004/10/22
Y1 - 2004/10/22
N2 - A study of ethylenediamine (en) complexes of Al, Ga, and In atoms prepared in laser vaporization supersonic molecular beams was presented. Using B3LYP calculations, several conformers of each metal complex were obtained. A five membered cyclic structure was also identified by combining the experimental measurements and theoretical calculations. Adiabatic ionization potentials, vibrational frequencies, and bond dissociation energies were also determined for the ring structure.
AB - A study of ethylenediamine (en) complexes of Al, Ga, and In atoms prepared in laser vaporization supersonic molecular beams was presented. Using B3LYP calculations, several conformers of each metal complex were obtained. A five membered cyclic structure was also identified by combining the experimental measurements and theoretical calculations. Adiabatic ionization potentials, vibrational frequencies, and bond dissociation energies were also determined for the ring structure.
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U2 - 10.1063/1.1791633
DO - 10.1063/1.1791633
M3 - Article
C2 - 15485228
AN - SCOPUS:8344267906
SN - 0021-9606
VL - 121
SP - 7692
EP - 7700
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
IS - 16
ER -