Poly-μ-2,5-dimethylpyrazine-μ-dithiocyanato-N, S,S-dicopper(I): A three-dimensional coordination polymer containing both molecular and anionic rod ligands

Tom Otieno; Jaime R. Blanton; Kena J. Lanham; Sean Parkin

doi:10.1023/A:1024265611094

Poly-μ-2,5-dimethylpyrazine-μ-dithiocyanato-N, S,S-dicopper(I): A three-dimensional coordination polymer containing both molecular and anionic rod ligands

Tom Otieno, Jaime R. Blanton, Kena J. Lanham, Sean Parkin

Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Reaction of CuSCN with 2,5-dimethylpyrazine (2,5-me₂pyz) yields a polymeric material, [Cu₂(SCN)₂(2,5-me ₂pyz)]∞, which has been crystallographically characterized. The compound crystallizes in the monoclinic space group P2₁/n with a = 5.6850(2) Å, b = 6.92877(3) Å, c = 14.3575(6) Å, β= 93.435(1)°, and Z = 2. It contains[Cu(SCN)]∞ sheets in which each thiocyanate ligand acts in a μ-N,S,S-bridging mode. The sheets are bridged by 2,5-dimethylpyrazine ligands to generate a three dimensional network. The compound has also been characterized by infrared spectroscopy and thermogravimetric analysis.

Original language	English
Pages (from-to)	335-339
Number of pages	5
Journal	Journal of Chemical Crystallography
Volume	33
Issue number	5-6
DOIs	https://doi.org/10.1023/A:1024265611094
State	Published - Jun 2003

Bibliographical note

Funding Information:
This work was supported by Eastern Kentucky University.

Funding

This work was supported by Eastern Kentucky University.

Funders	Funder number
Eastern Kentucky, University

Keywords

2,5-dimethylpyrazine
Coordination polymer
Copper(I) thiocyanate

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics

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@article{6c05f90424c747e3a792f3c70178e2bb,

title = "Poly-μ-2,5-dimethylpyrazine-μ-dithiocyanato-N, S,S-dicopper(I): A three-dimensional coordination polymer containing both molecular and anionic rod ligands",

abstract = "Reaction of CuSCN with 2,5-dimethylpyrazine (2,5-me2pyz) yields a polymeric material, [Cu2(SCN)2(2,5-me 2pyz)]∞, which has been crystallographically characterized. The compound crystallizes in the monoclinic space group P21/n with a = 5.6850(2) {\AA}, b = 6.92877(3) {\AA}, c = 14.3575(6) {\AA}, β= 93.435(1)°, and Z = 2. It contains[Cu(SCN)]∞ sheets in which each thiocyanate ligand acts in a μ-N,S,S-bridging mode. The sheets are bridged by 2,5-dimethylpyrazine ligands to generate a three dimensional network. The compound has also been characterized by infrared spectroscopy and thermogravimetric analysis.",

keywords = "2,5-dimethylpyrazine, Coordination polymer, Copper(I) thiocyanate",

author = "Tom Otieno and Blanton, \{Jaime R.\} and Lanham, \{Kena J.\} and Sean Parkin",

note = "Funding Information: This work was supported by Eastern Kentucky University.",

year = "2003",

month = jun,

doi = "10.1023/A:1024265611094",

language = "English",

volume = "33",

pages = "335--339",

number = "5-6",

}

TY - JOUR

T1 - Poly-μ-2,5-dimethylpyrazine-μ-dithiocyanato-N, S,S-dicopper(I)

T2 - A three-dimensional coordination polymer containing both molecular and anionic rod ligands

AU - Otieno, Tom

AU - Blanton, Jaime R.

AU - Lanham, Kena J.

AU - Parkin, Sean

N1 - Funding Information: This work was supported by Eastern Kentucky University.

PY - 2003/6

Y1 - 2003/6

N2 - Reaction of CuSCN with 2,5-dimethylpyrazine (2,5-me2pyz) yields a polymeric material, [Cu2(SCN)2(2,5-me 2pyz)]∞, which has been crystallographically characterized. The compound crystallizes in the monoclinic space group P21/n with a = 5.6850(2) Å, b = 6.92877(3) Å, c = 14.3575(6) Å, β= 93.435(1)°, and Z = 2. It contains[Cu(SCN)]∞ sheets in which each thiocyanate ligand acts in a μ-N,S,S-bridging mode. The sheets are bridged by 2,5-dimethylpyrazine ligands to generate a three dimensional network. The compound has also been characterized by infrared spectroscopy and thermogravimetric analysis.

AB - Reaction of CuSCN with 2,5-dimethylpyrazine (2,5-me2pyz) yields a polymeric material, [Cu2(SCN)2(2,5-me 2pyz)]∞, which has been crystallographically characterized. The compound crystallizes in the monoclinic space group P21/n with a = 5.6850(2) Å, b = 6.92877(3) Å, c = 14.3575(6) Å, β= 93.435(1)°, and Z = 2. It contains[Cu(SCN)]∞ sheets in which each thiocyanate ligand acts in a μ-N,S,S-bridging mode. The sheets are bridged by 2,5-dimethylpyrazine ligands to generate a three dimensional network. The compound has also been characterized by infrared spectroscopy and thermogravimetric analysis.

KW - 2,5-dimethylpyrazine

KW - Coordination polymer

KW - Copper(I) thiocyanate

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U2 - 10.1023/A:1024265611094

DO - 10.1023/A:1024265611094

M3 - Article

AN - SCOPUS:0038463645

SN - 1074-1542

VL - 33

SP - 335

EP - 339

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 5-6

ER -

Poly-μ-2,5-dimethylpyrazine-μ-dithiocyanato-N, S,S-dicopper(I): A three-dimensional coordination polymer containing both molecular and anionic rod ligands

Abstract

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Keywords

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