Polymorphism of an organic system effected by the directionality of hydrogen-bonding Chains

Sihui Long; Sean Parkin; Maxime Siegler; Carolyn P. Brock; Arthur Gammers; Tonglei Li

doi:10.1021/cg800339h

Polymorphism of an organic system effected by the directionality of hydrogen-bonding Chains

Sihui Long, Sean Parkin, Maxime Siegler, Carolyn P. Brock, Arthur Gammers, Tonglei Li

Chemistry

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Four polymorphs of 2-[methyl(phenyl)amino]nicotinic acid were discovered, and their single crystal structures were obtained at 90 K. In addition, one monohydrate and one salt were also crystallized and measured. Among the crystal structures, there are 17 crystallographically independent conformations. More interestingly, the four anhydrate forms are tessellated similarly by stacking of one-dimension hydrogen-bonding chains and, yet, the directionalities of the hydrogen-bonding chains are unique in each polymorph.

Original language	English
Pages (from-to)	3137-3140
Number of pages	4
Journal	Crystal Growth and Design
Volume	8
Issue number	9
DOIs	https://doi.org/10.1021/cg800339h
State	Published - Sep 2008

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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abstract = "Four polymorphs of 2-[methyl(phenyl)amino]nicotinic acid were discovered, and their single crystal structures were obtained at 90 K. In addition, one monohydrate and one salt were also crystallized and measured. Among the crystal structures, there are 17 crystallographically independent conformations. More interestingly, the four anhydrate forms are tessellated similarly by stacking of one-dimension hydrogen-bonding chains and, yet, the directionalities of the hydrogen-bonding chains are unique in each polymorph.",

author = "Sihui Long and Sean Parkin and Maxime Siegler and Brock, {Carolyn P.} and Arthur Gammers and Tonglei Li",

year = "2008",

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doi = "10.1021/cg800339h",

language = "English",

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T1 - Polymorphism of an organic system effected by the directionality of hydrogen-bonding Chains

AU - Long, Sihui

AU - Parkin, Sean

AU - Siegler, Maxime

AU - Brock, Carolyn P.

AU - Gammers, Arthur

AU - Li, Tonglei

PY - 2008/9

Y1 - 2008/9

N2 - Four polymorphs of 2-[methyl(phenyl)amino]nicotinic acid were discovered, and their single crystal structures were obtained at 90 K. In addition, one monohydrate and one salt were also crystallized and measured. Among the crystal structures, there are 17 crystallographically independent conformations. More interestingly, the four anhydrate forms are tessellated similarly by stacking of one-dimension hydrogen-bonding chains and, yet, the directionalities of the hydrogen-bonding chains are unique in each polymorph.

AB - Four polymorphs of 2-[methyl(phenyl)amino]nicotinic acid were discovered, and their single crystal structures were obtained at 90 K. In addition, one monohydrate and one salt were also crystallized and measured. Among the crystal structures, there are 17 crystallographically independent conformations. More interestingly, the four anhydrate forms are tessellated similarly by stacking of one-dimension hydrogen-bonding chains and, yet, the directionalities of the hydrogen-bonding chains are unique in each polymorph.

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DO - 10.1021/cg800339h

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JO - Crystal Growth and Design

JF - Crystal Growth and Design

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ER -

Polymorphism of an organic system effected by the directionality of hydrogen-bonding Chains

Abstract

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