Polyoxometalates functioned as ligands: Synthesis and crystal structure of a new hybrid compound constructed from metatungstate and metal complex units

Bangbo Yan; Yan Fen Li; Hou Yin Zhao; Wei Ping Pan; Sean Parkin

doi:10.1016/j.inoche.2009.09.009

Polyoxometalates functioned as ligands: Synthesis and crystal structure of a new hybrid compound constructed from metatungstate and metal complex units

Bangbo Yan, Yan Fen Li, Hou Yin Zhao, Wei Ping Pan, Sean Parkin

Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A new organic-inorganic hybrid compound, [Zn(bpy)₃]_1.5[H₃W₁₂O₄₀Zn(bpy)₂(H₂O)]·0.5H₂O (bpy = 2,2′-bipyridine) has been synthesized hydrothermally from ZnCl₂, Na₆[H₂W₁₂O₄₀], and 2,2′-bipyridine, and has been analyzed using X-ray crystallography, thermogravimetric analysis and UV-Vis spectroscopy. The compound contains an anionic complex [H₃W₁₂O₄₀Zn(bpy)₂(H₂O)]^3- in which α-metatungstate ion [H₃W₁₂O₄₀]^5- coordinated to a [Zn(bpy)₂(H₂O)]²⁺ unit through a bridging oxo group.

Original language	English
Pages (from-to)	1139-1141
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	12
Issue number	11
DOIs	https://doi.org/10.1016/j.inoche.2009.09.009
State	Published - Nov 2009

Bibliographical note

Funding Information:
Financial supports of this work by the Kentucky EPSCoR ( RSF-030-06 ), the WKU start-up grant and the WKU New Faculty Scholarship are greatly appreciated.

Copyright:
Copyright 2009 Elsevier B.V., All rights reserved.

Keywords

Crystal structure
Hydrothermal synthesis
Polyoxotungstate
Zinc

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.inoche.2009.09.009

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@article{dcdcd6b85f714aaf9a8a53a519b94afb,

title = "Polyoxometalates functioned as ligands: Synthesis and crystal structure of a new hybrid compound constructed from metatungstate and metal complex units",

abstract = "A new organic-inorganic hybrid compound, [Zn(bpy)3]1.5[H3W12O40Zn(bpy)2(H2O)]·0.5H2O (bpy = 2,2′-bipyridine) has been synthesized hydrothermally from ZnCl2, Na6[H2W12O40], and 2,2′-bipyridine, and has been analyzed using X-ray crystallography, thermogravimetric analysis and UV-Vis spectroscopy. The compound contains an anionic complex [H3W12O40Zn(bpy)2(H2O)]3- in which α-metatungstate ion [H3W12O40]5- coordinated to a [Zn(bpy)2(H2O)]2+ unit through a bridging oxo group.",

keywords = "Crystal structure, Hydrothermal synthesis, Polyoxotungstate, Zinc",

author = "Bangbo Yan and Li, {Yan Fen} and Zhao, {Hou Yin} and Pan, {Wei Ping} and Sean Parkin",

note = "Funding Information: Financial supports of this work by the Kentucky EPSCoR ( RSF-030-06 ), the WKU start-up grant and the WKU New Faculty Scholarship are greatly appreciated. Copyright: Copyright 2009 Elsevier B.V., All rights reserved.",

year = "2009",

month = nov,

doi = "10.1016/j.inoche.2009.09.009",

language = "English",

volume = "12",

pages = "1139--1141",

number = "11",

}

TY - JOUR

T1 - Polyoxometalates functioned as ligands

T2 - Synthesis and crystal structure of a new hybrid compound constructed from metatungstate and metal complex units

AU - Yan, Bangbo

AU - Li, Yan Fen

AU - Zhao, Hou Yin

AU - Pan, Wei Ping

AU - Parkin, Sean

N1 - Funding Information: Financial supports of this work by the Kentucky EPSCoR ( RSF-030-06 ), the WKU start-up grant and the WKU New Faculty Scholarship are greatly appreciated. Copyright: Copyright 2009 Elsevier B.V., All rights reserved.

PY - 2009/11

Y1 - 2009/11

N2 - A new organic-inorganic hybrid compound, [Zn(bpy)3]1.5[H3W12O40Zn(bpy)2(H2O)]·0.5H2O (bpy = 2,2′-bipyridine) has been synthesized hydrothermally from ZnCl2, Na6[H2W12O40], and 2,2′-bipyridine, and has been analyzed using X-ray crystallography, thermogravimetric analysis and UV-Vis spectroscopy. The compound contains an anionic complex [H3W12O40Zn(bpy)2(H2O)]3- in which α-metatungstate ion [H3W12O40]5- coordinated to a [Zn(bpy)2(H2O)]2+ unit through a bridging oxo group.

AB - A new organic-inorganic hybrid compound, [Zn(bpy)3]1.5[H3W12O40Zn(bpy)2(H2O)]·0.5H2O (bpy = 2,2′-bipyridine) has been synthesized hydrothermally from ZnCl2, Na6[H2W12O40], and 2,2′-bipyridine, and has been analyzed using X-ray crystallography, thermogravimetric analysis and UV-Vis spectroscopy. The compound contains an anionic complex [H3W12O40Zn(bpy)2(H2O)]3- in which α-metatungstate ion [H3W12O40]5- coordinated to a [Zn(bpy)2(H2O)]2+ unit through a bridging oxo group.

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Polyoxotungstate

KW - Zinc

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U2 - 10.1016/j.inoche.2009.09.009

DO - 10.1016/j.inoche.2009.09.009

M3 - Article

AN - SCOPUS:70350572903

SN - 1387-7003

VL - 12

SP - 1139

EP - 1141

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 11

ER -

Polyoxometalates functioned as ligands: Synthesis and crystal structure of a new hybrid compound constructed from metatungstate and metal complex units

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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