TY - JOUR
T1 - Preparation and structure of 3,4,8,9-tetrachloro-2,5,7,10-tetrahydro[1,6]dithiecine
AU - Eaton, David L.
AU - Selegue, John P.
AU - Anthony, John
AU - Patrick, Brian O.
PY - 2002/12/1
Y1 - 2002/12/1
N2 - The reaction of Z-1,4-dibromo-2,3-dichlorobut-2-ene (1) with sodium sulfide leads to 3,4,8,9-tetrachloro-2,5,7,10-tetrahydro[1,6]dithiecine (2) as the principal product, rather than the anticipated 3,4-dichloro-2,5-dihydrothiophene (3). Compound (2) was characterized spectroscopically and its structure determined by X-Ray crystallography.
AB - The reaction of Z-1,4-dibromo-2,3-dichlorobut-2-ene (1) with sodium sulfide leads to 3,4,8,9-tetrachloro-2,5,7,10-tetrahydro[1,6]dithiecine (2) as the principal product, rather than the anticipated 3,4-dichloro-2,5-dihydrothiophene (3). Compound (2) was characterized spectroscopically and its structure determined by X-Ray crystallography.
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U2 - 10.3987/com-02-9588
DO - 10.3987/com-02-9588
M3 - Article
AN - SCOPUS:0036899392
SN - 0385-5414
VL - 57
SP - 2373
EP - 2381
JO - Heterocycles
JF - Heterocycles
IS - 12
ER -