Pyromellitic diimide-based donor-acceptor poly(phenylene ethynylene)s

Xugang Guo, Mark D. Watson

Research output: Contribution to journalArticlepeer-review

78 Scopus citations

Abstract

A series of donor-acceptor poly(phenylene ethynylene)s (PPEs) with N,N′-dialkylpyromellitic diimide (PMDI) as electron acceptor and various donor units are reported. Optoelectronic properties were investigated by UV/vis absorption and electrochemical measurements, revealing constant LUMO energies (∼-3.6 eV) across the series with HOMO energy levels governed by the donor monomers and optical band gaps from 2.30 to 1.50 eV. With a high volume fraction of solubilizing side chains, the polymers are soluble in common organic solvents, but solution NMR measurements and thermochromism in solution indicate aggregation due to additive intermolecular interactions between donor and acceptor units.

Original languageEnglish
Pages (from-to)6711-6716
Number of pages6
JournalMacromolecules
Volume44
Issue number17
DOIs
StatePublished - Sep 13 2011

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint

Dive into the research topics of 'Pyromellitic diimide-based donor-acceptor poly(phenylene ethynylene)s'. Together they form a unique fingerprint.

Cite this