Recovery of rare earth elements (REEs), especially heavy and critical REEs, from alternative resources such as coal refuse has recently become increasingly important. A natural leachate containing 6.14 ppm of REEs with a pH value of 2.70 was collected from a coal coarse refuse pile and utilized as a feedstock for REE recovery tests. The pH value of the natural leachate was gradually increased in a step-wise manner using a sodium hydroxide solution which produced several precipitates. A precipitate containing about 1.1% total REEs was obtained in the pH range of 4.85–6.11 while recovering >80% of the REEs contained in the original leachate. The leaching and staged precipitation process enriched both the critical and heavy REE fractions. The ratios of heavy-to-light (H/L) and critical-to-uncritical (C/UC) REEs in the precipitate were much higher than the coarse refuse material (H/L: 1.54 vs 0.21, C/UC: 1.51 vs 0.34). Additionally, the precipitate contained 18.4% Al, 1.7% Zn, 1.4% Cu, 1.1% Mn, 0.5% Ni and 0.2% Co. A solution chemistry study indicated that the hydroxide and hydroxysulphate precipitates of Al, Si and Cu produced in the pH range of 4.85–6.11 contributed to the fractionation of the REEs and other metal ions such as Zn, Mn and Co to the precipitate. The iron hydroxide precipitates formed at lower pH values did not contain a significant amount of REEs. An explanation may be the competitive adsorption between Al, which was present at higher solution concentrations, and REEs on the iron hydroxide and/or hydroxysulphate precipitate surfaces as proven by results of precipitation tests conducted on model solutions. A product containing 94% of a rare earth oxide mix was obtained by re-dissolution of the REE enriched precipitates followed by selective precipitation using oxalic acid. The overall results including an economic assessment indicate that leachate solutions generated naturally from coarse coal refuse may be a valuable source of critical and heavy REEs that can be effectively recovered and concentrated using staged precipitation.
|Number of pages||11|
|Journal||International Journal of Coal Geology|
|State||Published - Jul 1 2018|
Bibliographical noteFunding Information:
This material is based upon work supported by the Department of Energy under Award Number DE-FE0027035 . Disclaimer: This report was prepared as an account of work sponsored by an agency of the United States Government . Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.
- Coal refuse
- Rare earth elements (REEs)
- Staged precipitation
ASJC Scopus subject areas
- Fuel Technology
- Economic Geology