Re-evaluating the role of sterics and electronic coupling in determining the open-circuit voltage of organic solar cells

Kenneth R. Graham; Patrick Erwin; Dennis Nordlund; Koen Vandewal; Ruipeng Li; Guy O. Ngongang Ndjawa; Eric T. Hoke; Alberto Salleo; Mark E. Thompson; Michael D. McGehee; Aram Amassian

doi:10.1002/adma.201301319

Re-evaluating the role of sterics and electronic coupling in determining the open-circuit voltage of organic solar cells

Kenneth R. Graham, Patrick Erwin, Dennis Nordlund, Koen Vandewal, Ruipeng Li, Guy O. Ngongang Ndjawa, Eric T. Hoke, Alberto Salleo, Mark E. Thompson, Michael D. McGehee, Aram Amassian

Chemistry

Research output: Contribution to journal › Article › peer-review

93 Scopus citations

Abstract

The effects of sterics and molecular orientation on the open-circuit voltage and absorbance properties of charge-transfer states are explored in model bilayer organic photovoltaics. It is shown that the open-circuit voltage correlates linearly with the charge-transfer state energy and is not significantly influenced by electronic coupling.

Original language	English
Pages (from-to)	6076-6082
Number of pages	7
Journal	Advanced Materials
Volume	25
Issue number	42
DOIs	https://doi.org/10.1002/adma.201301319
State	Published - Nov 13 2013

Keywords

charge-transfer state
electronic coupling
open-circuit voltage
organic photovoltaic
organic solar cell

ASJC Scopus subject areas

Materials Science (all)
Mechanics of Materials
Mechanical Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1002/adma.201301319

Cite this

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title = "Re-evaluating the role of sterics and electronic coupling in determining the open-circuit voltage of organic solar cells",

abstract = "The effects of sterics and molecular orientation on the open-circuit voltage and absorbance properties of charge-transfer states are explored in model bilayer organic photovoltaics. It is shown that the open-circuit voltage correlates linearly with the charge-transfer state energy and is not significantly influenced by electronic coupling.",

keywords = "charge-transfer state, electronic coupling, open-circuit voltage, organic photovoltaic, organic solar cell",

author = "Graham, {Kenneth R.} and Patrick Erwin and Dennis Nordlund and Koen Vandewal and Ruipeng Li and {Ngongang Ndjawa}, {Guy O.} and Hoke, {Eric T.} and Alberto Salleo and Thompson, {Mark E.} and McGehee, {Michael D.} and Aram Amassian",

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doi = "10.1002/adma.201301319",

language = "English",

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T1 - Re-evaluating the role of sterics and electronic coupling in determining the open-circuit voltage of organic solar cells

AU - Graham, Kenneth R.

AU - Erwin, Patrick

AU - Nordlund, Dennis

AU - Vandewal, Koen

AU - Li, Ruipeng

AU - Ngongang Ndjawa, Guy O.

AU - Hoke, Eric T.

AU - Salleo, Alberto

AU - Thompson, Mark E.

AU - McGehee, Michael D.

AU - Amassian, Aram

PY - 2013/11/13

Y1 - 2013/11/13

N2 - The effects of sterics and molecular orientation on the open-circuit voltage and absorbance properties of charge-transfer states are explored in model bilayer organic photovoltaics. It is shown that the open-circuit voltage correlates linearly with the charge-transfer state energy and is not significantly influenced by electronic coupling.

AB - The effects of sterics and molecular orientation on the open-circuit voltage and absorbance properties of charge-transfer states are explored in model bilayer organic photovoltaics. It is shown that the open-circuit voltage correlates linearly with the charge-transfer state energy and is not significantly influenced by electronic coupling.

KW - charge-transfer state

KW - electronic coupling

KW - open-circuit voltage

KW - organic photovoltaic

KW - organic solar cell

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UR - http://www.scopus.com/inward/citedby.url?scp=84887490084&partnerID=8YFLogxK

U2 - 10.1002/adma.201301319

DO - 10.1002/adma.201301319

M3 - Article

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SN - 0935-9648

VL - 25

SP - 6076

EP - 6082

JO - Advanced Materials

JF - Advanced Materials

IS - 42

ER -

Re-evaluating the role of sterics and electronic coupling in determining the open-circuit voltage of organic solar cells

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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