Reactions of heterocumulenes with triosmium clusters

Richard D. Adams; John P. Selegue

Reactions of heterocumulenes with triosmium clusters

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We have found that the cluster H₂Os₃(CO)₁₀ reacts with a variety of heterocumulenes via activation and hydrogen transfer to yield cluster complexes containing partially hydrogenated substrates variously coordinated to the polynuclear metal frameworks. CS₂ reacts with H₂Os₃(CO)₉-[P(CH₃)₂C ₆H₅] via a sequential transfer of two hydrogen atoms in a process that eventually leads to fragmentation of CS₂ substrate and the cluster.

Original language	English
Pages (from-to)	737-750
Number of pages	14
Journal	American Chemical Society, Division of Petroleum Chemistry, Preprints
Volume	25
Issue number	4
State	Published - 1980

ASJC Scopus subject areas

Fuel Technology

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title = "Reactions of heterocumulenes with triosmium clusters",

abstract = "We have found that the cluster H2Os3(CO)10 reacts with a variety of heterocumulenes via activation and hydrogen transfer to yield cluster complexes containing partially hydrogenated substrates variously coordinated to the polynuclear metal frameworks. CS2 reacts with H2Os3(CO)9-[P(CH3)2C 6H5] via a sequential transfer of two hydrogen atoms in a process that eventually leads to fragmentation of CS2 substrate and the cluster.",

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year = "1980",

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T1 - Reactions of heterocumulenes with triosmium clusters

AU - Adams, Richard D.

AU - Selegue, John P.

PY - 1980

Y1 - 1980

N2 - We have found that the cluster H2Os3(CO)10 reacts with a variety of heterocumulenes via activation and hydrogen transfer to yield cluster complexes containing partially hydrogenated substrates variously coordinated to the polynuclear metal frameworks. CS2 reacts with H2Os3(CO)9-[P(CH3)2C 6H5] via a sequential transfer of two hydrogen atoms in a process that eventually leads to fragmentation of CS2 substrate and the cluster.

AB - We have found that the cluster H2Os3(CO)10 reacts with a variety of heterocumulenes via activation and hydrogen transfer to yield cluster complexes containing partially hydrogenated substrates variously coordinated to the polynuclear metal frameworks. CS2 reacts with H2Os3(CO)9-[P(CH3)2C 6H5] via a sequential transfer of two hydrogen atoms in a process that eventually leads to fragmentation of CS2 substrate and the cluster.

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M3 - Article

AN - SCOPUS:33847086228

SN - 0569-3799

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JO - American Chemical Society, Division of Petroleum Chemistry, Preprints

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IS - 4

ER -

Reactions of heterocumulenes with triosmium clusters

Abstract

ASJC Scopus subject areas

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