Reactivity of a well-characterized titananorbornadiene (η6-arene) complex with ketones and aldehydes

Oleg V. Ozerov; Scan Parkin; Carolyn P. Brock; Folami T. Ladipo

doi:10.1021/om000410w

Reactivity of a well-characterized titananorbornadiene (η⁶-arene) complex with ketones and aldehydes

Oleg V. Ozerov, Scan Parkin, Carolyn P. Brock, Folami T. Ladipo

Chemistry

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

The reaction between the titananorbornadiene complex [(DMSC)Ti(η⁶-1,2,4-(Me₃Si)₃C₆H₃)] and ketones or aldehydes were proceeded by insertion of a ketone or aldehyde molecule into a Ti-C bond of 2,5-dioxatitanacyclopentane. The intermediacy of 2-oxatitanacycloheptene species and the formation of 2,5-dioxatitanacyclopentane compounds was also indicated.

Original language	English
Pages (from-to)	4187-4190
Number of pages	4
Journal	Organometallics
Volume	19
Issue number	21
DOIs	https://doi.org/10.1021/om000410w
State	Published - Oct 2000

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Reactivity of a well-characterized titananorbornadiene (η6-arene) complex with ketones and aldehydes",

abstract = "The reaction between the titananorbornadiene complex [(DMSC)Ti(η6-1,2,4-(Me3Si)3C6H3)] and ketones or aldehydes were proceeded by insertion of a ketone or aldehyde molecule into a Ti-C bond of 2,5-dioxatitanacyclopentane. The intermediacy of 2-oxatitanacycloheptene species and the formation of 2,5-dioxatitanacyclopentane compounds was also indicated.",

author = "Ozerov, {Oleg V.} and Scan Parkin and Brock, {Carolyn P.} and Ladipo, {Folami T.}",

year = "2000",

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doi = "10.1021/om000410w",

language = "English",

volume = "19",

pages = "4187--4190",

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T1 - Reactivity of a well-characterized titananorbornadiene (η6-arene) complex with ketones and aldehydes

AU - Ozerov, Oleg V.

AU - Parkin, Scan

AU - Brock, Carolyn P.

AU - Ladipo, Folami T.

PY - 2000/10

Y1 - 2000/10

N2 - The reaction between the titananorbornadiene complex [(DMSC)Ti(η6-1,2,4-(Me3Si)3C6H3)] and ketones or aldehydes were proceeded by insertion of a ketone or aldehyde molecule into a Ti-C bond of 2,5-dioxatitanacyclopentane. The intermediacy of 2-oxatitanacycloheptene species and the formation of 2,5-dioxatitanacyclopentane compounds was also indicated.

AB - The reaction between the titananorbornadiene complex [(DMSC)Ti(η6-1,2,4-(Me3Si)3C6H3)] and ketones or aldehydes were proceeded by insertion of a ketone or aldehyde molecule into a Ti-C bond of 2,5-dioxatitanacyclopentane. The intermediacy of 2-oxatitanacycloheptene species and the formation of 2,5-dioxatitanacyclopentane compounds was also indicated.

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JO - Organometallics

JF - Organometallics

IS - 21

ER -

Reactivity of a well-characterized titananorbornadiene (η⁶-arene) complex with ketones and aldehydes

Abstract

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