TY - JOUR
T1 - Relaxation dynamics in the presence of unequally spaced attractors along the reaction coordinate
AU - Despa, F.
AU - Berry, R. S.
PY - 2001/9
Y1 - 2001/9
N2 - We show how reaction coordinate path lengths affect the relaxation efficiency of a complex system. To this purpose, we consider the metric contributions to the transition rates. These metric contributions contain information about the system's change of geometry at the barrier crossing and, therefore, are directly related, differentially, to the path lengths. The results of this work can enrich the accuracy with which we describe how complex systems relax to preferential structures.
AB - We show how reaction coordinate path lengths affect the relaxation efficiency of a complex system. To this purpose, we consider the metric contributions to the transition rates. These metric contributions contain information about the system's change of geometry at the barrier crossing and, therefore, are directly related, differentially, to the path lengths. The results of this work can enrich the accuracy with which we describe how complex systems relax to preferential structures.
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U2 - 10.1007/s100530170059
DO - 10.1007/s100530170059
M3 - Article
AN - SCOPUS:0034258186
SN - 1434-6060
VL - 8
SP - 55
EP - 58
JO - European Physical Journal D
JF - European Physical Journal D
IS - 3
ER -