TY - JOUR
T1 - Reply to the 'Comment on "relating side chain organization of PNIPAm with its conformation in aqueous methanol"' by A. Pica and G. Graziano,
T2 - Soft Matter, 2017, 13, DOI: 10.1039/C7SM01065F
AU - Mukherji, Debashish
AU - Wagner, Manfred
AU - Watson, Mark D.
AU - Winzen, Svenja
AU - De Oliveira, Tiago E.
AU - Marques, Carlos M.
AU - Kremer, Kurt
N1 - Publisher Copyright:
© 2017 The Royal Society of Chemistry.
PY - 2017
Y1 - 2017
N2 - We have recently proposed preferential binding by a cosolvent as the mechanism for chain collapse under co-non-solvency. Here we summarise our earlier works and provide further evidence that alcohol preferentially binds to PNIPAm, forming cosolvent bridges, and thus drives the transition. We also clarify some of the common misconceptions evoked in this debate with Pica and Graziano (PG), reinforcing the arguments of our earlier reply-comment [Soft Matter, 2017, 13, 2292] and published works.
AB - We have recently proposed preferential binding by a cosolvent as the mechanism for chain collapse under co-non-solvency. Here we summarise our earlier works and provide further evidence that alcohol preferentially binds to PNIPAm, forming cosolvent bridges, and thus drives the transition. We also clarify some of the common misconceptions evoked in this debate with Pica and Graziano (PG), reinforcing the arguments of our earlier reply-comment [Soft Matter, 2017, 13, 2292] and published works.
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UR - http://www.scopus.com/inward/citedby.url?scp=85032724934&partnerID=8YFLogxK
U2 - 10.1039/c7sm01880k
DO - 10.1039/c7sm01880k
M3 - Review article
C2 - 29057420
AN - SCOPUS:85032724934
SN - 1744-683X
VL - 13
SP - 7701
EP - 7703
JO - Soft Matter
JF - Soft Matter
IS - 42
ER -