Review on carbon dioxide utilization for cycloaddition of epoxides by ionic liquid-modified hybrid catalysts: Effect of influential parameters and mechanisms insight

Jimmy Nelson Appaturi; Rajabathar Jothi Ramalingam; Muthu Kumaran Gnanamani; Govindasami Periyasami; Prabhakarn Arunachalam; Rohana Adnan; Farook Adam; Mohammed D. Wasmiah; Hamad A. Al-Lohedan

doi:10.3390/catal11010004

Review on carbon dioxide utilization for cycloaddition of epoxides by ionic liquid-modified hybrid catalysts: Effect of influential parameters and mechanisms insight

Jimmy Nelson Appaturi, Rajabathar Jothi Ramalingam, Muthu Kumaran Gnanamani, Govindasami Periyasami, Prabhakarn Arunachalam, Rohana Adnan, Farook Adam, Mohammed D. Wasmiah, Hamad A. Al-Lohedan

Center for Applied Energy Research (CAER)

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The storage, utilization, and control of the greenhouse (CO₂) gas is a topic of interest for researchers in academia and society. The present review article is dedicating to cover the overall role of ionic liquid-modified hybrid materials in cycloaddition reactions. Special emphasis is on the synthesis of various cyclic carbonate using ionic liquid-based modified catalysts. Catalytic activity studies have discussed with respect to process conditions and their effects on conversion and product selectivity for the reaction of cycloaddition of CO₂ with styrene oxide. The reaction temperature and the partial pressure of CO₂ have found to play a key role in cyclic carbonate formation. The role of other influential parameter (solvent effect) is also discussed for the conversion of cyclic/aromatic oxides to polycarbonate production. Our own research work that deals with ionic liquid-based halide-modified mesoporous catalyst (MCM-41 type) derived from rice husk waste has also been discussed. Finally, the role of carbon dioxide activation and ring-opening mechanisms involved in the cyclic carbonate product formation from CO₂ have been discussed.

Original language	English
Article number	4
Pages (from-to)	1-15
Number of pages	15
Journal	Catalysts
Volume	11
Issue number	1
DOIs	https://doi.org/10.3390/catal11010004
State	Published - Jan 2021

Bibliographical note

Funding Information:
Acknowledgments: The authors acknowledge the Deputyship for Research & Innovation, “Ministry of Education” in Saudi Arabia for funding this research work through the project number IFKSURP-335.

Publisher Copyright:
© 2020 by the authors. Licensee MDPI, Basel, Switzerland.

Funding

Acknowledgments: The authors acknowledge the Deputyship for Research & Innovation, “Ministry of Education” in Saudi Arabia for funding this research work through the project number IFKSURP-335.

Funders	Funder number
Ministry of Education – Kingdom of Saudi Arabi	IFKSURP-335

Keywords

Cycloaddition
Greenhouse gas
Ionic liquid
Mesoporous silica
Poly-carbonate

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry

Access to Document

10.3390/catal11010004

Cite this

Appaturi, J. N., Ramalingam, R. J., Gnanamani, M. K., Periyasami, G., Arunachalam, P., Adnan, R., Adam, F., Wasmiah, M. D., & Al-Lohedan, H. A. (2021). Review on carbon dioxide utilization for cycloaddition of epoxides by ionic liquid-modified hybrid catalysts: Effect of influential parameters and mechanisms insight. Catalysts, 11(1), 1-15. Article 4. https://doi.org/10.3390/catal11010004

@article{6462ad40d20a4c8e9af39a2154c44da8,

title = "Review on carbon dioxide utilization for cycloaddition of epoxides by ionic liquid-modified hybrid catalysts: Effect of influential parameters and mechanisms insight",

abstract = "The storage, utilization, and control of the greenhouse (CO2) gas is a topic of interest for researchers in academia and society. The present review article is dedicating to cover the overall role of ionic liquid-modified hybrid materials in cycloaddition reactions. Special emphasis is on the synthesis of various cyclic carbonate using ionic liquid-based modified catalysts. Catalytic activity studies have discussed with respect to process conditions and their effects on conversion and product selectivity for the reaction of cycloaddition of CO2 with styrene oxide. The reaction temperature and the partial pressure of CO2 have found to play a key role in cyclic carbonate formation. The role of other influential parameter (solvent effect) is also discussed for the conversion of cyclic/aromatic oxides to polycarbonate production. Our own research work that deals with ionic liquid-based halide-modified mesoporous catalyst (MCM-41 type) derived from rice husk waste has also been discussed. Finally, the role of carbon dioxide activation and ring-opening mechanisms involved in the cyclic carbonate product formation from CO2 have been discussed.",

keywords = "Cycloaddition, Greenhouse gas, Ionic liquid, Mesoporous silica, Poly-carbonate",

author = "Appaturi, {Jimmy Nelson} and Ramalingam, {Rajabathar Jothi} and Gnanamani, {Muthu Kumaran} and Govindasami Periyasami and Prabhakarn Arunachalam and Rohana Adnan and Farook Adam and Wasmiah, {Mohammed D.} and Al-Lohedan, {Hamad A.}",

note = "Funding Information: Acknowledgments: The authors acknowledge the Deputyship for Research & Innovation, “Ministry of Education” in Saudi Arabia for funding this research work through the project number IFKSURP-335. Publisher Copyright: {\textcopyright} 2020 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2021",

month = jan,

doi = "10.3390/catal11010004",

language = "English",

volume = "11",

pages = "1--15",

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Appaturi, JN, Ramalingam, RJ, Gnanamani, MK, Periyasami, G, Arunachalam, P, Adnan, R, Adam, F, Wasmiah, MD & Al-Lohedan, HA 2021, 'Review on carbon dioxide utilization for cycloaddition of epoxides by ionic liquid-modified hybrid catalysts: Effect of influential parameters and mechanisms insight', Catalysts, vol. 11, no. 1, 4, pp. 1-15. https://doi.org/10.3390/catal11010004

Review on carbon dioxide utilization for cycloaddition of epoxides by ionic liquid-modified hybrid catalysts: Effect of influential parameters and mechanisms insight. / Appaturi, Jimmy Nelson; Ramalingam, Rajabathar Jothi; Gnanamani, Muthu Kumaran et al.
In: Catalysts, Vol. 11, No. 1, 4, 01.2021, p. 1-15.

Research output: Contribution to journal › Article › peer-review

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T2 - Effect of influential parameters and mechanisms insight

AU - Appaturi, Jimmy Nelson

AU - Ramalingam, Rajabathar Jothi

AU - Gnanamani, Muthu Kumaran

AU - Periyasami, Govindasami

AU - Arunachalam, Prabhakarn

AU - Adnan, Rohana

AU - Adam, Farook

AU - Wasmiah, Mohammed D.

AU - Al-Lohedan, Hamad A.

N1 - Funding Information: Acknowledgments: The authors acknowledge the Deputyship for Research & Innovation, “Ministry of Education” in Saudi Arabia for funding this research work through the project number IFKSURP-335. Publisher Copyright: © 2020 by the authors. Licensee MDPI, Basel, Switzerland.

PY - 2021/1

Y1 - 2021/1

N2 - The storage, utilization, and control of the greenhouse (CO2) gas is a topic of interest for researchers in academia and society. The present review article is dedicating to cover the overall role of ionic liquid-modified hybrid materials in cycloaddition reactions. Special emphasis is on the synthesis of various cyclic carbonate using ionic liquid-based modified catalysts. Catalytic activity studies have discussed with respect to process conditions and their effects on conversion and product selectivity for the reaction of cycloaddition of CO2 with styrene oxide. The reaction temperature and the partial pressure of CO2 have found to play a key role in cyclic carbonate formation. The role of other influential parameter (solvent effect) is also discussed for the conversion of cyclic/aromatic oxides to polycarbonate production. Our own research work that deals with ionic liquid-based halide-modified mesoporous catalyst (MCM-41 type) derived from rice husk waste has also been discussed. Finally, the role of carbon dioxide activation and ring-opening mechanisms involved in the cyclic carbonate product formation from CO2 have been discussed.

AB - The storage, utilization, and control of the greenhouse (CO2) gas is a topic of interest for researchers in academia and society. The present review article is dedicating to cover the overall role of ionic liquid-modified hybrid materials in cycloaddition reactions. Special emphasis is on the synthesis of various cyclic carbonate using ionic liquid-based modified catalysts. Catalytic activity studies have discussed with respect to process conditions and their effects on conversion and product selectivity for the reaction of cycloaddition of CO2 with styrene oxide. The reaction temperature and the partial pressure of CO2 have found to play a key role in cyclic carbonate formation. The role of other influential parameter (solvent effect) is also discussed for the conversion of cyclic/aromatic oxides to polycarbonate production. Our own research work that deals with ionic liquid-based halide-modified mesoporous catalyst (MCM-41 type) derived from rice husk waste has also been discussed. Finally, the role of carbon dioxide activation and ring-opening mechanisms involved in the cyclic carbonate product formation from CO2 have been discussed.

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KW - Greenhouse gas

KW - Ionic liquid

KW - Mesoporous silica

KW - Poly-carbonate

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Review on carbon dioxide utilization for cycloaddition of epoxides by ionic liquid-modified hybrid catalysts: Effect of influential parameters and mechanisms insight

Abstract

Bibliographical note

Funding

Keywords

ASJC Scopus subject areas

Access to Document

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