Robust, soluble pentacene ethers

Marcia M. Payne; Jared H. Delcamp; Sean R. Parkin; John E. Anthony

doi:10.1021/ol049593z

Robust, soluble pentacene ethers

Marcia M. Payne
, Jared H. Delcamp
, Sean R. Parkin
, John E. Anthony

Chemistry

Research output: Contribution to journal › Article › peer-review

110 Scopus citations

Abstract

We report the synthesis and characterization of a series of alkoxy-substituted silylethynylated pentacene derivatives (R = CH ₂CH₂, CHCH, CH₂). All three compounds are easily prepared, soluble in common organic solvents, and stable both as solids and in solution. Two of the derivatives possess significant π-face interactions in the crystal. Values for λ_max for these new pentacene derivatives range from 621 to 674 nm, and oxidation potentials lie between 109 and 301 mV versus ferrocene.

Original language	English
Pages (from-to)	1609-1612
Number of pages	4
Journal	Organic Letters
Volume	6
Issue number	10
DOIs	https://doi.org/10.1021/ol049593z
State	Published - May 13 2004

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "Robust, soluble pentacene ethers",

abstract = "We report the synthesis and characterization of a series of alkoxy-substituted silylethynylated pentacene derivatives (R = CH 2CH2, CHCH, CH2). All three compounds are easily prepared, soluble in common organic solvents, and stable both as solids and in solution. Two of the derivatives possess significant π-face interactions in the crystal. Values for λmax for these new pentacene derivatives range from 621 to 674 nm, and oxidation potentials lie between 109 and 301 mV versus ferrocene.",

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T1 - Robust, soluble pentacene ethers

AU - Payne, Marcia M.

AU - Delcamp, Jared H.

AU - Parkin, Sean R.

AU - Anthony, John E.

PY - 2004/5/13

Y1 - 2004/5/13

N2 - We report the synthesis and characterization of a series of alkoxy-substituted silylethynylated pentacene derivatives (R = CH 2CH2, CHCH, CH2). All three compounds are easily prepared, soluble in common organic solvents, and stable both as solids and in solution. Two of the derivatives possess significant π-face interactions in the crystal. Values for λmax for these new pentacene derivatives range from 621 to 674 nm, and oxidation potentials lie between 109 and 301 mV versus ferrocene.

AB - We report the synthesis and characterization of a series of alkoxy-substituted silylethynylated pentacene derivatives (R = CH 2CH2, CHCH, CH2). All three compounds are easily prepared, soluble in common organic solvents, and stable both as solids and in solution. Two of the derivatives possess significant π-face interactions in the crystal. Values for λmax for these new pentacene derivatives range from 621 to 674 nm, and oxidation potentials lie between 109 and 301 mV versus ferrocene.

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UR - https://www.scopus.com/pages/publications/2542612351#tab=citedBy

U2 - 10.1021/ol049593z

DO - 10.1021/ol049593z

M3 - Article

C2 - 15128248

AN - SCOPUS:2542612351

SN - 1523-7060

VL - 6

SP - 1609

EP - 1612

JO - Organic Letters

JF - Organic Letters

IS - 10

ER -

Robust, soluble pentacene ethers

Abstract

ASJC Scopus subject areas

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