RuII complexes of "large-surface" ligands

Edith C. Glazer; Yitzhak Tor

doi:10.1002/1521-3773(20021104)41:21<4022::AID-ANIE4022>3.0.CO;2-1

Ru^II complexes of "large-surface" ligands

Edith C. Glazer, Yitzhak Tor

Chemistry

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

The fabrication of Ru^II-polypyridyl complexes with "large-surface" ligands can be achieved by utilizing metal coordination to facilitate a dehydrogenation reaction (see scheme), This modular methodology efficiently yields biologically active eilatin-containing complexes, as well as Ru^II complexes of previously unknown ligands.

Original language	English
Pages (from-to)	4022-4026
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	21
DOIs	https://doi.org/10.1002/1521-3773(20021104)41:21<4022::AID-ANIE4022>3.0.CO;2-1
State	Published - Nov 4 2002

Keywords

Bridging ligands
Dehydrogenation
Ligand design
N ligands
Ruthenium

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/1521-3773(20021104)41:21<4022::AID-ANIE4022>3.0.CO;2-1

Cite this

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abstract = "The fabrication of RuII-polypyridyl complexes with {"}large-surface{"} ligands can be achieved by utilizing metal coordination to facilitate a dehydrogenation reaction (see scheme), This modular methodology efficiently yields biologically active eilatin-containing complexes, as well as RuII complexes of previously unknown ligands.",

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AU - Tor, Yitzhak

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AB - The fabrication of RuII-polypyridyl complexes with "large-surface" ligands can be achieved by utilizing metal coordination to facilitate a dehydrogenation reaction (see scheme), This modular methodology efficiently yields biologically active eilatin-containing complexes, as well as RuII complexes of previously unknown ligands.

KW - Bridging ligands

KW - Dehydrogenation

KW - Ligand design

KW - N ligands

KW - Ruthenium

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AN - SCOPUS:0037020554

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JF - Angewandte Chemie - International Edition

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