TY - JOUR
T1 - Salvinicins A and B, new neoclerodane diterpenes from Salvia divinorum
AU - Harding, Wayne W.
AU - Tidgewell, Kevin
AU - Schmidt, Matthew
AU - Shah, Kushal
AU - Dersch, Christina M.
AU - Snyder, John
AU - Parrish, Damon
AU - Deschamps, Jeffrey R.
AU - Rothman, Richard B.
AU - Prisinzano, Thomas E.
PY - 2005/7/7
Y1 - 2005/7/7
N2 - (Chemical Equation Presented) Two new neoclerodane diterpenes, salvinicins A (4) and B (5), were isolated from the dried leaves of Salvia divinorum. The structures of these compounds were elucidated by spectroscopic techniques, including 1H and 13C NMR, NOESY, HMQC, and HMBC. The absolute stereochemistry of these compounds was assigned on the basis of single-crystal X-ray crystallographic analysis of salvinicin A (4) and a 3,4-dichlorobenzoate derivative of salvinorin B.
AB - (Chemical Equation Presented) Two new neoclerodane diterpenes, salvinicins A (4) and B (5), were isolated from the dried leaves of Salvia divinorum. The structures of these compounds were elucidated by spectroscopic techniques, including 1H and 13C NMR, NOESY, HMQC, and HMBC. The absolute stereochemistry of these compounds was assigned on the basis of single-crystal X-ray crystallographic analysis of salvinicin A (4) and a 3,4-dichlorobenzoate derivative of salvinorin B.
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U2 - 10.1021/ol0510522
DO - 10.1021/ol0510522
M3 - Article
C2 - 15987194
AN - SCOPUS:22244466770
SN - 1523-7060
VL - 7
SP - 3017
EP - 3020
JO - Organic Letters
JF - Organic Letters
IS - 14
ER -