Size and Dopant Dependent Single Particle Fluorescence Properties of Graphene Quantum Dots

Somes K. Das, Chi Man Luk, William E. Martin, Libin Tang, Doo Young Kim, Shu Ping Lau, Christopher I. Richards

Research output: Contribution to journalArticlepeer-review

54 Scopus citations

Abstract

The emissive properties of both doped and nondoped graphene quantum dots (GQDs) with sizes ranging from 3 to 11 nm were analyzed at the single particle level. Both doped and nondoped GQDs are a composite of particles exhibiting green, red, or NIR fluorescence on excitation at 488, 561, and 640 nm, respectively. Nitrogen-doped GQDs (N-GQDs) with diameters ranging from 3.4 to 5.2 nm show a larger proportion of particles with NIR emission as compared to nondoped particles. Doping of GQDs also resulted in changes in the photostability and the fluorescence intermittency seen in single GQD particles. While milliseconds to seconds time scale blinking was regularly observed for red-emitting nondoped GQDs, nitrogen doping significantly reduced blinking. Both doped and nondoped particles also exhibit moderate size dependent photophysical properties.

Original languageEnglish
Pages (from-to)17988-17994
Number of pages7
JournalJournal of Physical Chemistry C
Volume119
Issue number31
DOIs
StatePublished - Aug 6 2015

Bibliographical note

Publisher Copyright:
© 2015 American Chemical Society.

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • General Energy
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

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