Solubility and Thermodynamic Modeling of Carcinogenic Nitrosamines in Aqueous Amine Solvents for CO2 Capture

Jesse Thompson; Naser Matin; Kunlei Liu

doi:10.1016/j.egypro.2017.03.1250

Solubility and Thermodynamic Modeling of Carcinogenic Nitrosamines in Aqueous Amine Solvents for CO₂ Capture

Jesse Thompson
, Naser Matin
, Kunlei Liu

Research output: Contribution to journal › Conference article › peer-review

4 Scopus citations

Abstract

A better understanding of key fundamental properties of nitrosamines, including their solubility in aqueous amine solvents, is needed to understand and accurately model the vapor-phase emission levels from operating CO2 capture systems. In this work, the first experimental Henry's volatility coefficient of a nitrosamine was obtained with a novel method using static headspace solid phase micro extraction (SPME) and gas chromatography mass spectrometry (GC/MS). The experimentally determined Henry's volatility coefficient of nitrosopyrrolidine (NPY) was found to be around 0.02 (dimensionless) at 25 °C, and falls in the range of a semi-volatile compound. A linear temperature dependency of the Henry's volatility coefficient can be observed, however additional data is need to verify this trend. Published by Elsevier Ltd.

Original language	English
Pages (from-to)	1038-1044
Number of pages	7
Journal	Energy Procedia
Volume	114
DOIs	https://doi.org/10.1016/j.egypro.2017.03.1250
State	Published - 2017
Event	13th International Conference on Greenhouse Gas Control Technologies, GHGT 2016 - Lausanne, Switzerland Duration: Nov 14 2016 → Nov 18 2016

Bibliographical note

Publisher Copyright:
© 2017 The Authors.

Funding

The authors acknowledge the Carbon Management Research Group (CMRG) members, including Duke Energy, Electric Power Research Institute (EPRI), Kentucky Department of Energy Development and Independence (KY-DEDI), and Louisville Gas & Electric (LG&E) and Kentucky Utilities (KU) for their financial support.

Funders
Kentucky Department for Energy Development and Independence
Kentucky Utilities Company
Electric Power Research Institute, Louisville Gas & Electric
Duke Energy
Electric Power Research Institute, Louisville Gas & Electric

Keywords

CO capture
Henry's volatility coefficient
Nitrosamine
SPME

ASJC Scopus subject areas

General Energy

Access to Document

10.1016/j.egypro.2017.03.1250

Cite this

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title = "Solubility and Thermodynamic Modeling of Carcinogenic Nitrosamines in Aqueous Amine Solvents for CO2 Capture",

abstract = "A better understanding of key fundamental properties of nitrosamines, including their solubility in aqueous amine solvents, is needed to understand and accurately model the vapor-phase emission levels from operating CO2 capture systems. In this work, the first experimental Henry's volatility coefficient of a nitrosamine was obtained with a novel method using static headspace solid phase micro extraction (SPME) and gas chromatography mass spectrometry (GC/MS). The experimentally determined Henry's volatility coefficient of nitrosopyrrolidine (NPY) was found to be around 0.02 (dimensionless) at 25 °C, and falls in the range of a semi-volatile compound. A linear temperature dependency of the Henry's volatility coefficient can be observed, however additional data is need to verify this trend. Published by Elsevier Ltd.",

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AU - Matin, Naser

AU - Liu, Kunlei

PY - 2017

Y1 - 2017

N2 - A better understanding of key fundamental properties of nitrosamines, including their solubility in aqueous amine solvents, is needed to understand and accurately model the vapor-phase emission levels from operating CO2 capture systems. In this work, the first experimental Henry's volatility coefficient of a nitrosamine was obtained with a novel method using static headspace solid phase micro extraction (SPME) and gas chromatography mass spectrometry (GC/MS). The experimentally determined Henry's volatility coefficient of nitrosopyrrolidine (NPY) was found to be around 0.02 (dimensionless) at 25 °C, and falls in the range of a semi-volatile compound. A linear temperature dependency of the Henry's volatility coefficient can be observed, however additional data is need to verify this trend. Published by Elsevier Ltd.

AB - A better understanding of key fundamental properties of nitrosamines, including their solubility in aqueous amine solvents, is needed to understand and accurately model the vapor-phase emission levels from operating CO2 capture systems. In this work, the first experimental Henry's volatility coefficient of a nitrosamine was obtained with a novel method using static headspace solid phase micro extraction (SPME) and gas chromatography mass spectrometry (GC/MS). The experimentally determined Henry's volatility coefficient of nitrosopyrrolidine (NPY) was found to be around 0.02 (dimensionless) at 25 °C, and falls in the range of a semi-volatile compound. A linear temperature dependency of the Henry's volatility coefficient can be observed, however additional data is need to verify this trend. Published by Elsevier Ltd.

KW - CO capture

KW - Henry's volatility coefficient

KW - Nitrosamine

KW - SPME

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DO - 10.1016/j.egypro.2017.03.1250

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