Solvent-free olefin metathesis depolymerization of 1,4-polybutadiene

Mark D. Watson; Kenneth B. Wagener

doi:10.1021/ma991560p

Solvent-free olefin metathesis depolymerization of 1,4-polybutadiene

Mark D. Watson, Kenneth B. Wagener

Chemistry

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

The well-defined ruthenium catalyst, Cl₂(Cy₃P)₂RuCHPh (1) was found to effect the clean metathesis depolymerization of high molecular weight 1,4-polybutadiene at room temperature. Further, the role of the 1,2-repeat units in intramolecular chain limitation was delineated.

Original language	English
Pages (from-to)	1494-1496
Number of pages	3
Journal	Macromolecules
Volume	33
Issue number	5
DOIs	https://doi.org/10.1021/ma991560p
State	Published - Mar 7 2000

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma991560p

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title = "Solvent-free olefin metathesis depolymerization of 1,4-polybutadiene",

abstract = "The well-defined ruthenium catalyst, Cl2(Cy3P)2RuCHPh (1) was found to effect the clean metathesis depolymerization of high molecular weight 1,4-polybutadiene at room temperature. Further, the role of the 1,2-repeat units in intramolecular chain limitation was delineated.",

author = "Watson, {Mark D.} and Wagener, {Kenneth B.}",

year = "2000",

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doi = "10.1021/ma991560p",

language = "English",

volume = "33",

pages = "1494--1496",

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T1 - Solvent-free olefin metathesis depolymerization of 1,4-polybutadiene

AU - Watson, Mark D.

AU - Wagener, Kenneth B.

PY - 2000/3/7

Y1 - 2000/3/7

N2 - The well-defined ruthenium catalyst, Cl2(Cy3P)2RuCHPh (1) was found to effect the clean metathesis depolymerization of high molecular weight 1,4-polybutadiene at room temperature. Further, the role of the 1,2-repeat units in intramolecular chain limitation was delineated.

AB - The well-defined ruthenium catalyst, Cl2(Cy3P)2RuCHPh (1) was found to effect the clean metathesis depolymerization of high molecular weight 1,4-polybutadiene at room temperature. Further, the role of the 1,2-repeat units in intramolecular chain limitation was delineated.

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U2 - 10.1021/ma991560p

DO - 10.1021/ma991560p

M3 - Article

AN - SCOPUS:0033907030

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VL - 33

SP - 1494

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JO - Macromolecules

JF - Macromolecules

IS - 5

ER -

Solvent-free olefin metathesis depolymerization of 1,4-polybutadiene

Abstract

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