Stabilization of the [AlMe2]⊕ Cation by Crown Ethers

Simon G. Bott; Abbas Alvanipour; S. David Morley; David A. Atwood; C. Mitchell Means; Anthony W. Coleman; Jerry L. Atwood

doi:10.1002/anie.198704851

Stabilization of the [AlMe₂]^⊕ Cation by Crown Ethers

Simon G. Bott, Abbas Alvanipour, S. David Morley, David A. Atwood, C. Mitchell Means, Anthony W. Coleman, Jerry L. Atwood

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

Of interest for Ziegler–Natta systems with donor ligands are the structures of the cations of 1 and 2. The cation [AlMe₂]^⊕ is encapsulated by crown ethers and in 1 is bound to three of the six oxygen atoms while in 2 it is bound to all five oxygen atoms; the MeAlMe angle in 1 is 141^°, in 2 178^°. (1 contains [18]crown‐6, 2 contains [15]crown‐5.) (Formula Presented.)

Original language	English
Pages (from-to)	485-486
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	26
Issue number	5
DOIs	https://doi.org/10.1002/anie.198704851
State	Published - May 1987

ASJC Scopus subject areas

Catalysis
General Chemistry

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title = "Stabilization of the [AlMe2]⊕ Cation by Crown Ethers",

abstract = "Of interest for Ziegler–Natta systems with donor ligands are the structures of the cations of 1 and 2. The cation [AlMe2]⊕ is encapsulated by crown ethers and in 1 is bound to three of the six oxygen atoms while in 2 it is bound to all five oxygen atoms; the MeAlMe angle in 1 is 141°, in 2 178°. (1 contains [18]crown‐6, 2 contains [15]crown‐5.) (Formula Presented.)",

author = "Bott, {Simon G.} and Abbas Alvanipour and Morley, {S. David} and Atwood, {David A.} and Means, {C. Mitchell} and Coleman, {Anthony W.} and Atwood, {Jerry L.}",

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language = "English",

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T1 - Stabilization of the [AlMe2]⊕ Cation by Crown Ethers

AU - Bott, Simon G.

AU - Alvanipour, Abbas

AU - Morley, S. David

AU - Atwood, David A.

AU - Means, C. Mitchell

AU - Coleman, Anthony W.

AU - Atwood, Jerry L.

PY - 1987/5

Y1 - 1987/5

N2 - Of interest for Ziegler–Natta systems with donor ligands are the structures of the cations of 1 and 2. The cation [AlMe2]⊕ is encapsulated by crown ethers and in 1 is bound to three of the six oxygen atoms while in 2 it is bound to all five oxygen atoms; the MeAlMe angle in 1 is 141°, in 2 178°. (1 contains [18]crown‐6, 2 contains [15]crown‐5.) (Formula Presented.)

AB - Of interest for Ziegler–Natta systems with donor ligands are the structures of the cations of 1 and 2. The cation [AlMe2]⊕ is encapsulated by crown ethers and in 1 is bound to three of the six oxygen atoms while in 2 it is bound to all five oxygen atoms; the MeAlMe angle in 1 is 141°, in 2 178°. (1 contains [18]crown‐6, 2 contains [15]crown‐5.) (Formula Presented.)

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Stabilization of the [AlMe₂]^⊕ Cation by Crown Ethers

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