TY - JOUR
T1 - Stable Soluble Conjugated Carbon Rods with a Persilylethynylated Polytriacetylene Backbone
AU - Anthony, John
AU - Boudon, Corinne
AU - Diederich, François
AU - Gisselbrecht, Jean‐Paul ‐P
AU - Gramlich, Volker
AU - Gross, Maurice
AU - Hobi, Markus
AU - Seiler, Paul
PY - 1994/4/18
Y1 - 1994/4/18
N2 - Carbon rods 1‐5 up to five nanometers long are formed by oxidative polymerization of trans‐bis(triisopropylsilyl)‐protected tetraethynylethene with phenylacetylene as end‐capping reagent. The X‐ray crystal structures of 1 and 2 show perfectly planar, conjugated carbon frames. Compounds 1–5 are readily reduced; the number of reversible one‐electron reductions equals the number of tetraethynylethene moieties in each molecular rod. TIPS = triisopropylsilyl. (Figure Presented.)
AB - Carbon rods 1‐5 up to five nanometers long are formed by oxidative polymerization of trans‐bis(triisopropylsilyl)‐protected tetraethynylethene with phenylacetylene as end‐capping reagent. The X‐ray crystal structures of 1 and 2 show perfectly planar, conjugated carbon frames. Compounds 1–5 are readily reduced; the number of reversible one‐electron reductions equals the number of tetraethynylethene moieties in each molecular rod. TIPS = triisopropylsilyl. (Figure Presented.)
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U2 - 10.1002/anie.199407631
DO - 10.1002/anie.199407631
M3 - Article
AN - SCOPUS:4544232576
SN - 0570-0833
VL - 33
SP - 763
EP - 766
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 7
ER -