Structural characterization of a dialkylgallium cation: X-ray crystal structure of [Me2Ga(tBuNH2)2]Br

David A. Atwood; Richard A. Jones; Alan H. Cowley; Simon G. Bott; Jerry L. Atwood

doi:10.1016/0022-328X(92)80037-X

Structural characterization of a dialkylgallium cation: X-ray crystal structure of [Me₂Ga(^tBuNH₂)₂]Br

David A. Atwood, Richard A. Jones, Alan H. Cowley, Simon G. Bott, Jerry L. Atwood

Chemistry

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The X-ray crystal structure of [Me₂Ga(^tBuNH₂)₂]Br (1) has been determined. The compound was prepared in a 51% yield via the reaction of t-BuNH₂ with Me₂GaBr in Et₂O solution. The solid state of 1 consists of [Me₂Ga(^tBuNH₂)₂)⁺ cations and bromide anions. The gallium cation adopts a highly distorted tetrahedral geometry with Me(1)-Ga-Me(2) and N(1)-Ga-N(2) angles of 121.5(5) and 95.6(3)°, respectively.

Original language	English
Pages (from-to)	C1-C3
Journal	Journal of Organometallic Chemistry
Volume	425
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(92)80037-X
State	Published - Feb 25 1992

Bibliographical note

Funding Information:
Acknowledgements. We are grateful to the National Science Foundation and the Robert A. Welch Foundation for generousf inancial support.

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/0022-328X(92)80037-X

Cite this

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title = "Structural characterization of a dialkylgallium cation: X-ray crystal structure of [Me2Ga(tBuNH2)2]Br",

abstract = "The X-ray crystal structure of [Me2Ga(tBuNH2)2]Br (1) has been determined. The compound was prepared in a 51% yield via the reaction of t-BuNH2 with Me2GaBr in Et2O solution. The solid state of 1 consists of [Me2Ga(tBuNH2)2)+ cations and bromide anions. The gallium cation adopts a highly distorted tetrahedral geometry with Me(1)-Ga-Me(2) and N(1)-Ga-N(2) angles of 121.5(5) and 95.6(3)°, respectively.",

author = "Atwood, {David A.} and Jones, {Richard A.} and Cowley, {Alan H.} and Bott, {Simon G.} and Atwood, {Jerry L.}",

note = "Funding Information: Acknowledgements. We are grateful to the National Science Foundation and the Robert A. Welch Foundation for generousf inancial support.",

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T1 - Structural characterization of a dialkylgallium cation

T2 - X-ray crystal structure of [Me2Ga(tBuNH2)2]Br

AU - Atwood, David A.

AU - Jones, Richard A.

AU - Cowley, Alan H.

AU - Bott, Simon G.

AU - Atwood, Jerry L.

N1 - Funding Information: Acknowledgements. We are grateful to the National Science Foundation and the Robert A. Welch Foundation for generousf inancial support.

PY - 1992/2/25

Y1 - 1992/2/25

N2 - The X-ray crystal structure of [Me2Ga(tBuNH2)2]Br (1) has been determined. The compound was prepared in a 51% yield via the reaction of t-BuNH2 with Me2GaBr in Et2O solution. The solid state of 1 consists of [Me2Ga(tBuNH2)2)+ cations and bromide anions. The gallium cation adopts a highly distorted tetrahedral geometry with Me(1)-Ga-Me(2) and N(1)-Ga-N(2) angles of 121.5(5) and 95.6(3)°, respectively.

AB - The X-ray crystal structure of [Me2Ga(tBuNH2)2]Br (1) has been determined. The compound was prepared in a 51% yield via the reaction of t-BuNH2 with Me2GaBr in Et2O solution. The solid state of 1 consists of [Me2Ga(tBuNH2)2)+ cations and bromide anions. The gallium cation adopts a highly distorted tetrahedral geometry with Me(1)-Ga-Me(2) and N(1)-Ga-N(2) angles of 121.5(5) and 95.6(3)°, respectively.

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