Structures of pentakis-(imidazole)copper(II) hexafluoroarsenate monohydrate and chlorotetrakis-(imidazole)copper(II) chloride

Tom Otieno; Michael J. Hatfield; Sherry L. Asher; Angela I. McMullin; Brian O. Patrick; Sean Parkin

doi:10.1081/SIM-100107705

Structures of pentakis-(imidazole)copper(II) hexafluoroarsenate monohydrate and chlorotetrakis-(imidazole)copper(II) chloride

Tom Otieno, Michael J. Hatfield, Sherry L. Asher, Angela I. McMullin, Brian O. Patrick, Sean Parkin

Chemistry

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The complexes [Cu(imH)₅](AsF₆)₂·H₂O and [Cu(imH)₄Cl]Cl (imH = imidazole) were prepared and characterized on the basis of elemental analyses, infrared spectroscopy, electronic spectroscopy, magnetic moment measurements and X-ray crystallography. The complex cation in each species contains a five-coordinate copper atom with a distorted square-pyramidal geometry.

Original language	English
Pages (from-to)	1587-1598
Number of pages	12
Journal	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Volume	31
Issue number	9
DOIs	https://doi.org/10.1081/SIM-100107705
State	Published - 2001

Bibliographical note

Funding Information:
This work was supported by Eastern Kentucky University.

Funding

This work was supported by Eastern Kentucky University.

Funders	Funder number
Eastern Kentucky, University

ASJC Scopus subject areas

Inorganic Chemistry

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10.1081/SIM-100107705

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title = "Structures of pentakis-(imidazole)copper(II) hexafluoroarsenate monohydrate and chlorotetrakis-(imidazole)copper(II) chloride",

abstract = "The complexes [Cu(imH)5](AsF6)2·H2O and [Cu(imH)4Cl]Cl (imH = imidazole) were prepared and characterized on the basis of elemental analyses, infrared spectroscopy, electronic spectroscopy, magnetic moment measurements and X-ray crystallography. The complex cation in each species contains a five-coordinate copper atom with a distorted square-pyramidal geometry.",

author = "Tom Otieno and Hatfield, {Michael J.} and Asher, {Sherry L.} and McMullin, {Angela I.} and Patrick, {Brian O.} and Sean Parkin",

note = "Funding Information: This work was supported by Eastern Kentucky University.",

year = "2001",

doi = "10.1081/SIM-100107705",

language = "English",

volume = "31",

pages = "1587--1598",

number = "9",

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T1 - Structures of pentakis-(imidazole)copper(II) hexafluoroarsenate monohydrate and chlorotetrakis-(imidazole)copper(II) chloride

AU - Otieno, Tom

AU - Hatfield, Michael J.

AU - Asher, Sherry L.

AU - McMullin, Angela I.

AU - Patrick, Brian O.

AU - Parkin, Sean

N1 - Funding Information: This work was supported by Eastern Kentucky University.

PY - 2001

Y1 - 2001

N2 - The complexes [Cu(imH)5](AsF6)2·H2O and [Cu(imH)4Cl]Cl (imH = imidazole) were prepared and characterized on the basis of elemental analyses, infrared spectroscopy, electronic spectroscopy, magnetic moment measurements and X-ray crystallography. The complex cation in each species contains a five-coordinate copper atom with a distorted square-pyramidal geometry.

AB - The complexes [Cu(imH)5](AsF6)2·H2O and [Cu(imH)4Cl]Cl (imH = imidazole) were prepared and characterized on the basis of elemental analyses, infrared spectroscopy, electronic spectroscopy, magnetic moment measurements and X-ray crystallography. The complex cation in each species contains a five-coordinate copper atom with a distorted square-pyramidal geometry.

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U2 - 10.1081/SIM-100107705

DO - 10.1081/SIM-100107705

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JO - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

JF - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

IS - 9

ER -

Structures of pentakis-(imidazole)copper(II) hexafluoroarsenate monohydrate and chlorotetrakis-(imidazole)copper(II) chloride

Abstract

Bibliographical note

Funding

ASJC Scopus subject areas

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