Synergetic effects of inorganic components in solid electrolyte interphase on high cycle efficiency of lithium ion batteries

Qinglin Zhang; Peng Lu; Zhongyi Liu; Mark W. Verbrugge; Xingcheng Xiao; Jie Pan; Yang Tse Cheng; Brian W. Sheldon; Yue Qi

Synergetic effects of inorganic components in solid electrolyte interphase on high cycle efficiency of lithium ion batteries

Qinglin Zhang
, Peng Lu
, Zhongyi Liu
, Mark W. Verbrugge
, Xingcheng Xiao
, Jie Pan
, Yang Tse Cheng
, Brian W. Sheldon
, Yue Qi

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

3 Scopus citations

Abstract

The solid electrolyte interphase (SEI), a passivation layer formed on electrodes, is critical to battery performance and durability. The inorganic components in SEI, including lithium carbonate (Li2CO3) and lithium fluoride (LiF), provides both mechanical and chemical protection, meanwhile controls lithium ion transport. Although both Li2CO3 and LiF have relatively low ionic conductivity, we surprisingly found that the contact between Li2CO3 and LiF can promote space charge accumulation along their interfaces, which generates a higher ionic carrier concentration and significantly improves lithium ion transport and reduces electron leakage. The synergetic effect of the two inorganic components leads to high current efficiency and long cycle stability.

Original language	English
Title of host publication	Battery Congress 2016
ISBN (Electronic)	9781510825635
State	Published - 2016
Event	Battery Congress 2016 - Troy, United States Duration: May 16 2016 → May 18 2016

Publication series

Name	Battery Congress 2016

Conference

Conference	Battery Congress 2016
Country/Territory	United States
City	Troy
Period	5/16/16 → 5/18/16

Funding

Funders	Funder number
U.S. Department of Energy Chinese Academy of Sciences Guangzhou Municipal Science and Technology Project Oak Ridge National Laboratory Extreme Science and Engineering Discovery Environment National Science Foundation National Energy Research Scientific Computing Center National Natural Science Foundation of China	1355438

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

ASJC Scopus subject areas

Energy Engineering and Power Technology
Fuel Technology

Cite this

@inproceedings{37137ce229c04c92b1a495f3951bc268,

title = "Synergetic effects of inorganic components in solid electrolyte interphase on high cycle efficiency of lithium ion batteries",

abstract = "The solid electrolyte interphase (SEI), a passivation layer formed on electrodes, is critical to battery performance and durability. The inorganic components in SEI, including lithium carbonate (Li2CO3) and lithium fluoride (LiF), provides both mechanical and chemical protection, meanwhile controls lithium ion transport. Although both Li2CO3 and LiF have relatively low ionic conductivity, we surprisingly found that the contact between Li2CO3 and LiF can promote space charge accumulation along their interfaces, which generates a higher ionic carrier concentration and significantly improves lithium ion transport and reduces electron leakage. The synergetic effect of the two inorganic components leads to high current efficiency and long cycle stability.",

author = "Qinglin Zhang and Peng Lu and Zhongyi Liu and Verbrugge, \{Mark W.\} and Xingcheng Xiao and Jie Pan and Cheng, \{Yang Tse\} and Sheldon, \{Brian W.\} and Yue Qi",

year = "2016",

language = "English",

series = "Battery Congress 2016",

booktitle = "Battery Congress 2016",

note = "Battery Congress 2016 ; Conference date: 16-05-2016 Through 18-05-2016",

}

TY - GEN

T1 - Synergetic effects of inorganic components in solid electrolyte interphase on high cycle efficiency of lithium ion batteries

AU - Zhang, Qinglin

AU - Lu, Peng

AU - Liu, Zhongyi

AU - Verbrugge, Mark W.

AU - Xiao, Xingcheng

AU - Pan, Jie

AU - Cheng, Yang Tse

AU - Sheldon, Brian W.

AU - Qi, Yue

PY - 2016

Y1 - 2016

N2 - The solid electrolyte interphase (SEI), a passivation layer formed on electrodes, is critical to battery performance and durability. The inorganic components in SEI, including lithium carbonate (Li2CO3) and lithium fluoride (LiF), provides both mechanical and chemical protection, meanwhile controls lithium ion transport. Although both Li2CO3 and LiF have relatively low ionic conductivity, we surprisingly found that the contact between Li2CO3 and LiF can promote space charge accumulation along their interfaces, which generates a higher ionic carrier concentration and significantly improves lithium ion transport and reduces electron leakage. The synergetic effect of the two inorganic components leads to high current efficiency and long cycle stability.

AB - The solid electrolyte interphase (SEI), a passivation layer formed on electrodes, is critical to battery performance and durability. The inorganic components in SEI, including lithium carbonate (Li2CO3) and lithium fluoride (LiF), provides both mechanical and chemical protection, meanwhile controls lithium ion transport. Although both Li2CO3 and LiF have relatively low ionic conductivity, we surprisingly found that the contact between Li2CO3 and LiF can promote space charge accumulation along their interfaces, which generates a higher ionic carrier concentration and significantly improves lithium ion transport and reduces electron leakage. The synergetic effect of the two inorganic components leads to high current efficiency and long cycle stability.

UR - https://www.scopus.com/pages/publications/84983249742

UR - https://www.scopus.com/pages/publications/84983249742#tab=citedBy

M3 - Conference contribution

AN - SCOPUS:84983249742

T3 - Battery Congress 2016

BT - Battery Congress 2016

T2 - Battery Congress 2016

Y2 - 16 May 2016 through 18 May 2016

ER -

Synergetic effects of inorganic components in solid electrolyte interphase on high cycle efficiency of lithium ion batteries

Abstract

Publication series

Conference

Funding

UN SDGs

ASJC Scopus subject areas

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